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Raman spectra and phase transitions in Rb 2 KInF 6 elpasolite

Raman spectra and phase transitions in Rb 2 KInF 6 elpasolite Abstract The Raman spectra of Rb2KInF6 elpasolite crystal have been studied in a wide temperature range, including two phase transitions: from the cubic phase to the tetragonal phase and then to the monoclinic phase. Several anomalies of internal modes of InF6 octahedra and low-frequency lattice vibrations, which are related to the structural changes at the transition points, have been found and quantitatively analyzed. The results of a quantitative analysis of the temperature dependences of the parameters of spectral lines are in good agreement with the thermodynamic data on the phase transitions. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Crystallography Reports Springer Journals

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References (7)

Publisher
Springer Journals
Copyright
2011 Pleiades Publishing, Ltd.
ISSN
1063-7745
eISSN
1562-689X
DOI
10.1134/s1063774511010159
Publisher site
See Article on Publisher Site

Abstract

Abstract The Raman spectra of Rb2KInF6 elpasolite crystal have been studied in a wide temperature range, including two phase transitions: from the cubic phase to the tetragonal phase and then to the monoclinic phase. Several anomalies of internal modes of InF6 octahedra and low-frequency lattice vibrations, which are related to the structural changes at the transition points, have been found and quantitatively analyzed. The results of a quantitative analysis of the temperature dependences of the parameters of spectral lines are in good agreement with the thermodynamic data on the phase transitions.

Journal

Crystallography ReportsSpringer Journals

Published: Jan 1, 2011

Keywords: Crystallography and Scattering Methods

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