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Abstract The structure type of analcime (ANA) is interpreted based on the basic block: a six-membered ring of tetrahedra which is generated by two template cations. The uncertainties in the composition and/or structure of alumophosphate, ferrisilicate, and titanosilicate pollucites, which are complicated by adding H2O molecules and (OH)− or O2− anions, are eliminated. The block isomorphism and formation of super-structures in these pollucites is discussed. In view of the transformation of tetrahedral ANA frameworks into mixed ones, we propose that they be considered analcimoidal (quasipollucites).
Crystallography Reports – Springer Journals
Published: Sep 1, 2009
Keywords: Crystallography and Scattering Methods
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