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Prototropic Tautomerism of Salicylideneimines. Crystal Structure of 3,5-Dichlorosalicylideneallylimine

Prototropic Tautomerism of Salicylideneimines. Crystal Structure of... Azomethine, derived from 3,5-dichlorosalicylaldehyde and allylamine, was synthesized and studied by X-ray diffraction. The compound exists in the enol-imine tautomeric form (the hydrogen atom is located on the oxygen atom). The structure is stabilized by the intramolecular О(1)–Н(1А)···N(1) hydrogen bond (О–Н, 0.82 Å; H···N, 1.91 Å; O···N, 2.580 Å; О–H–N, 138°). http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Crystallography Reports Springer Journals

Prototropic Tautomerism of Salicylideneimines. Crystal Structure of 3,5-Dichlorosalicylideneallylimine

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Publisher
Springer Journals
Copyright
Copyright © Pleiades Publishing, Inc. 2020
ISSN
1063-7745
eISSN
1562-689X
DOI
10.1134/S106377452001023X
Publisher site
See Article on Publisher Site

Abstract

Azomethine, derived from 3,5-dichlorosalicylaldehyde and allylamine, was synthesized and studied by X-ray diffraction. The compound exists in the enol-imine tautomeric form (the hydrogen atom is located on the oxygen atom). The structure is stabilized by the intramolecular О(1)–Н(1А)···N(1) hydrogen bond (О–Н, 0.82 Å; H···N, 1.91 Å; O···N, 2.580 Å; О–H–N, 138°).

Journal

Crystallography ReportsSpringer Journals

Published: Jan 25, 2020

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