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- Publisher
- Springer Journals
- Copyright
- Copyright © 2017 by Springer-Verlag GmbH Germany
- Subject
- Chemistry; Electrochemistry; Renewable and Green Energy; Optical and Electronic Materials; Condensed Matter Physics; Energy Storage
- ISSN
- 0947-7047
- eISSN
- 1862-0760
- DOI
- 10.1007/s11581-017-2275-7
- Publisher site
- See Article on Publisher Site
Abstract
A mesoporous carbon (MC) is prepared by the method of hard-template. Cathode materials (S/MC) for Li-S battery were synthesized. Properties of S, MC, and S/MC were characterized by BET, XRD, Raman, HRTEM, and FESEM. Electrochemical performances of the batteries were determined by AC impedance, cyclic voltammetry, and constant-current charging and discharging. Experiments show that MC, prepared with mass ratio CaCO3/PVA = 1/1.5, is the most suitable for Li-S battery. Thereby, the battery shows initial specific capacity of 1383.6 mAh/g and 881.6 mAh/g after 100 cycles, and the Coulombic efficiencies are both over 98% after 100 cycles at the current rate of 0.5 and 1 C.
Journal
Ionics – Springer Journals
Published: Sep 24, 2017