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J. Ran, Liang Wu, Yubin He, Zhengjin Yang, Yaoming Wang, Chenxiao Jiang, Liang Ge, Erigene Bakangura, T. Xu (2017)
Ion exchange membranes: New developments and applicationsJournal of Membrane Science, 522
Steffen Hink, Ngoc Duong, D. Henkensmeier, J. Kim, J. Jang, Hyoung‐Juhn Kim, Jonghee Han, S. Nam (2015)
Radel-based membranes with pyridine and imidazole side groups for high temperature polymer electrolyte fuel cellsSolid State Ionics, 275
Qingfeng Li, J. Jensen, C. Pan, V. Bandur, M. Nilsson, F. Schönberger, A. Chromik, M. Hein, T. Häring, J. Kerres, N. Bjerrum (2008)
Partially Fluorinated Aarylene Polyethers and their Ternary Blends with PBI and H3PO4. Part II. Characterisation and Fuel Cell Tests of the Ternary MembranesFuel Cells, 8
Xin Xu, Haining Wang, Shanfu Lu, Zhibin Guo, Siyuan Rao, Ruijie Xiu, Yan Xiang (2015)
A novel phosphoric acid doped poly(ethersulphone)-poly(vinyl pyrrolidone) blend membrane for high-temperature proton exchange membrane fuel cellsJournal of Power Sources, 286
Wenjia Ma, Chengji Zhao, Jingshuai Yang, Jing Ni, Shuang Wang, N. Zhang, Haidan Lin, Jing Wang, Gang Zhang, Qingfeng Li, H. Na (2012)
Cross-linked aromatic cationic polymer electrolytes with enhanced stability for high temperature fuel cell applicationsEnergy and Environmental Science, 5
Q. Yuan, Ping Liu, G. Baker (2015)
Sulfonated polyimide and PVDF based blend proton exchange membranes for fuel cell applicationsJournal of Materials Chemistry, 3
Qingfeng Li, J. Jensen, R. Savinell, N. Bjerrum (2009)
High temperature proton exchange membranes based on polybenzimidazoles for fuel cellsProgress in Polymer Science, 34
Jingshuai Yang, Wang Yihan, Guopeng Yang, Si-Ying Zhan (2018)
New anhydrous proton exchange membranes based on fluoropolymers blend imidazolium poly (aromatic ether ketone)s for high temperature polymer electrolyte fuel cellsInternational Journal of Hydrogen Energy, 43
R. He, Qingfeng Li, A. Bach, J. Jensen, N. Bjerrum (2006)
Physicochemical properties of phosphoric acid doped polybenzimidazole membranes for fuel cellsJournal of Membrane Science, 277
Jingshuai Yang, Liping Gao, Jin Wang, Yixin Xu, Chao Liu, R. He (2017)
Strengthening Phosphoric Acid Doped Polybenzimidazole Membranes with Siloxane Networks for Using as High Temperature Proton Exchange MembranesMacromolecular Chemistry and Physics, 218
A. Chandan, M. Hattenberger, A. El-kharouf, S. Du, A. Dhir, V. Self, B. Pollet, A. Ingram, W. Bujalski (2013)
High temperature (HT) polymer electrolyte membrane fuel cells (PEMFC) – A reviewJournal of Power Sources, 231
Konstantinia Papadimitriou, Maria Geormezi, S. Neophytides, J. Kallitsis (2013)
Covalent cross-linking in phosphoric acid of pyridine based aromatic polyethers bearing side double bonds for use in high temperature polymer electrolyte membrane fuelcellsJournal of Membrane Science, 433
Zhaohua Li, Le Liu, Lihong Yu, Lei Wang, Jingyu Xi, X. Qiu, Liquan Chen (2014)
Characterization of sulfonated poly(ether ether ketone)/poly(vinylidene fluoride-co-hexafluoropropylene) composite membrane for vanadium redox flow battery applicationJournal of Power Sources, 272
Zhibin Guo, Xin Xu, Yan Xiang, Shanfu Lu, S. Jiang (2015)
New anhydrous proton exchange membranes for high-temperature fuel cells based on PVDF–PVP blended polymersJournal of Materials Chemistry, 3
J. Yang, L. Cleemann, T. Steenberg, C. Terkelsen, Q. Li, J. Jensen, H. Hjuler, N. Bjerrum, R. He (2014)
High Molecular Weight Polybenzimidazole Membranes for High Temperature PEMFCFuel Cells, 14
Jingshuai Yang, Yixin Xu, Lu Zhou, Quantong Che, R. He, Qingfeng Li (2013)
Hydroxyl pyridine containing polybenzimidazole membranes for proton exchange membrane fuel cellsJournal of Membrane Science, 446
Kyung Sung, Wan-Keun Kim, Keun-Hwan Oh, Min-ju Choo, Kwan-Woo Nam, Jung-Ki Park (2011)
Stability enhancement of polymer electrolyte membrane fuel cells based on a sulfonated poly(ether etThe Lancet
Ki‐Hyun Kim, Seong-Woo Choi, Jung Park, Sung‐Kon Kim, Min-young Lim, Taeyun Ko, Jong‐Chan Lee (2017)
Proton conductive cross-linked benzoxazine-benzimidazole copolymers as novel porous substrates for reinforced pore-filling membranes in fuel cells operating at high temperaturesJournal of Membrane Science, 536
J. Melchior, G. Majer, K. Kreuer (2017)
Why do proton conducting polybenzimidazole phosphoric acid membranes perform well in high-temperature PEM fuel cells?Physical chemistry chemical physics : PCCP, 19 1
Jingshuai Yang, Qingfeng Li, J. Jensen, C. Pan, L. Cleemann, N. Bjerrum, R. He (2012)
Phosphoric acid doped imidazolium polysulfone membranes for high temperature proton exchange membrane fuel cellsJournal of Power Sources, 205
Qing Li, Lei Liu, S. Liang, Qianbiao Li, Bang-kun Jin, Ruke Bai (2014)
A novel poly(2,6-dimethyl-1,4-phenylene oxide) with pendant imidazolium groups for high-temperature proton exchange membranePolymer Chemistry, 5
Jingshuai Yang, Qingfeng Li, L. Cleemann, J. Jensen, C. Pan, N. Bjerrum, R. He (2013)
Crosslinked Hexafluoropropylidene Polybenzimidazole Membranes with Chloromethyl Polysulfone for Fuel Cell ApplicationsAdvanced Energy Materials, 3
A. Bozkurt, W. Meyer (2001)
Proton-Conducting Poly(vinylpyrrolidon)-Polyphosphoric Acid BlendsJournal of Polymer Science Part B, 39
H. Pu, Qi-zhi Liu, Lei Qiao, Zhenglong Yang (2005)
Studies on proton conductivity of acid doped polybenzimidazole/polyimide and polybenzimidazole/polyvinylpyrrolidone blendsPolymer Engineering and Science, 45
Jiangpeng Ni, Meishao Hu, Dong Liu, Huixiong Xie, X. Xiang, Lei Wang (2016)
Synthesis and properties of highly branched polybenzimidazoles as proton exchange membranes for high-temperature fuel cellsJournal of Materials Chemistry C, 4
Qingfeng Li, R. He, R. Berg, H. Hjuler, N. Bjerrum (2004)
Water uptake and acid doping of polybenzimidazoles as electrolyte membranes for fuel cellsSolid State Ionics, 168
M. Daletou, Nora Gourdoupi, J. Kallitsis (2005)
Proton conducting membranes based on blends of PBI with aromatic polyethers containing pyridine unitsJournal of Membrane Science, 252
W. Li, J. Ye, Sam Li (2001)
Electrochemical deposition of Copper on patterned Cu/Ta(N)/SiO2 surfaces for super filling of sub-micron featuresJournal of Applied Electrochemistry, 31
G. Giffin, S. Galbiati, M. Walter, K. Aniol, Corina Ellwein, J. Kerres, R. Zeis (2017)
Interplay between structure and properties in acid-base blend PBI-based membranes for HT-PEM fuel cellsJournal of Membrane Science, 535
F. Schönberger, G. Qian, B. Benicewicz (2017)
Polybenzimidazole‐based block copolymers: From monomers to membrane electrode assemblies for high temperature polymer electrolyte membrane fuel cellsJournal of Polymer Science Part A, 55
Jing Wang, Jifu Zheng, Zhuo‐An Zhao, Suobo Zhang (2012)
Synthesis and characterization of a novel poly(arylene ether sulfone) containing pendent imidazole groups for high temperature proton exchange membranesJournal of Materials Chemistry, 22
(2013)
Polym
Mousumi Hazarika, T. Jana (2013)
Novel proton exchange membrane for fuel cell developed from blends of polybenzimidazole with fluorinated polymerEuropean Polymer Journal, 49
Jingshuai Yang, D. Aili, Qingfeng Li, L. Cleemann, J. Jensen, N. Bjerrum, R. He (2013)
Covalently cross-linked sulfone polybenzimidazole membranes with poly(vinylbenzyl chloride) for fuel cell applications.ChemSusChem, 6 2
D. Aili, L. Cleemann, Qingfeng Li, J. Jensen, E. Christensen, N. Bjerrum (2012)
Thermal curing of PBI membranes for high temperature PEM fuel cellsJournal of Materials Chemistry, 22
R. He, Quantong Che, Baoying Sun (2008)
The acid doping behavior of polybenzimidazole membranes in phosphoric acid for proton exchange membrane fuel cellsFibers and Polymers, 9
D. Joseph, N. Krishnan, D. Henkensmeier, Jong Jang, Sun Choi, Hyoung‐Juhn Kim, Jonghee Han, Suk Nam (2017)
Thermal crosslinking of PBI/sulfonated polysulfone based blend membranesJournal of Materials Chemistry, 5
Y. Ma, J. Wainright, M. Litt, R. Savinell (2004)
Conductivity of PBI Membranes for High-Temperature Polymer Electrolyte Fuel CellsJournal of The Electrochemical Society, 151
S. Mollá, V. Compañ, S. Lafuente, J. Prats (2011)
On the Methanol Permeability through Pristine Nafion® and Nafion/PVA Membranes Measured by Different Techniques. A Comparison of MethodologiesFuel Cells, 11
S. Singha, T. Jana (2014)
Effect of composition on the properties of PEM based on polybenzimidazole and poly(vinylidene fluoride) blendsPolymer, 55
Zhihong Si, F. Gu, Jiangna Guo, Feng Yan (2013)
Phosphoric acid‐doped imidazolium ionomers with enhanced stability for anhydrous proton‐exchange membrane applicationsJournal of Polymer Science Part B, 51
V. Noto, E. Negro, Jean‐Yves Sanchez, C. Iojoiu (2010)
Structure-relaxation interplay of a new nanostructured membrane based on tetraethylammonium trifluoromethanesulfonate ionic liquid and neutralized nafion 117 for high-temperature fuel cells.Journal of the American Chemical Society, 132 7
Simone Angioni, D. Villa, A. Cattaneo, P. Mustarelli, E. Quartarone (2015)
Influence of variously functionalized SBA-15 fillers on conductivity and electrochemical properties of PBI composite membranes for high temperature polymer fuel cellsJournal of Power Sources, 294
N. Zhang, Baolong Wang, Chengji Zhao, Shuang Wang, Yurong Zhang, F. Bu, Ying Cui, Xuefeng Li, H. Na (2014)
Quaternized poly (ether ether ketone)s doped with phosphoric acid for high-temperature polymer electrolyte membrane fuel cellsJournal of Materials Chemistry, 2
J. Kerres (2005)
Blended and Cross‐Linked Ionomer Membranes for Application in Membrane Fuel CellsFuel Cells, 5
Yuan-Cheng Cao, Chenxi Xu, Linling Zou, K. Scott, Jiyan Liu (2015)
A polytetrafluoroethylene porous membrane and dimethylhexadecylamine quaternized poly (vinyl benzyl chloride) composite membrane for intermediate temperature fuel cellsJournal of Power Sources, 294
Qingfeng Li, H. Hjuler, N. Bjerrum (2001)
Phosphoric acid doped polybenzimidazole membranes: Physiochemical characterization and fuel cell applicationsJournal of Applied Electrochemistry, 31
Song Xue, Geping Yin (2006)
Proton exchange membranes based on poly(vinylidene fluoride) and sulfonated poly(ether ether ketone)Polymer, 47
Abstract Poly(vinylpyrrolidone) (PVP), as the low-cost and commercial material, exhibits superior phosphoric acid doping capability due to the presence of heterocycle and carbonyl groups in the repeat unit. However, it can’t be used as the high temperature polymer electrolyte membrane (HT-PEM) alone because of its significant hydrophilicity and poor mechanical stability. In the present work, polyethersulfone (PES), polysulfone (PSU), polyetherketone-cardo (PEK-c), polyvinylidene fluoride (PVDF) and poly(vinylidene fluoride-co-hexafluoropropylene) (PHFP), five kinds of engineering thermoplastics with excellent mechanical properties and chemical inertness, are chosen to prepare a series of PVP blend membranes by the polymer blending method in order to enhance the dimensional and mechanical stabilities of PVP based membranes. The influence of structures of enhanced polymers on properties of HT-PEMs was investigated systematically. PVP blend membranes with aromatic polymers (i.e. PES, PSU and PEK-c) exhibited decreased volume swellings, increased acid doping contents, superior conductivities and improved mechanical strengths, which determined that they are more suitable for electrolytes of fuel cell applications comparing with PVP/PVDF and PVP/PHFP membranes blended with aliphatic polymers.
Fibers and Polymers – Springer Journals
Published: Dec 1, 2018
Keywords: Polymer Sciences
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