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Doklady Chemistry, Vol. 388, Nos. 4–6, 2003, pp. 39–43. Translated from Doklady Akademii Nauk, Vol. 388, No. 4, 2003, pp. 488–492. Original Russian Text Copyright © 2003 by Vasil’kov, Pribytkov, Lisichkin. CHEMISTRY Phenanthrene as a Ligand in the Synthesis of Sandwich Mono- and Binuclear Chromium Complexes A. Yu. Vasil’kov*, P. V. Pribytkov*, and G. V. Lisichkin** Presented by Academician Yu.N. Bubnov October 25, 2002 Received October 31, 2002 Sandwich mono- and binuclear chromium p -com- new mono- and binuclear sandwich chromium com- plexes are of interest not only for the study of funda- plexes with phenanthrene. This process was analyzed in mental aspects of the variation of properties of an detail and the properties of the compounds obtained organic molecule under the action of metal coordina- were investigated. tion, but also as convenient models for the understand- The reaction of chromium atoms with phenanthrene ing of intramolecular electron transfer from the metal to may give a mixture of mono- and binuclear complexes ligand or between metal nuclei [1, 2]. 11Ð13 (see Scheme 1). Analysis of the reaction prod- The first sandwich chromium complex with a poly- ucts showed that, both in an earlier publication [12] and cyclic aromatic hydrocarbon
Doklady Chemistry – Springer Journals
Published: Oct 5, 2004
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