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Phase Equilibria in the Li2O–Al2O3–Ni–Co–O System

Phase Equilibria in the Li2O–Al2O3–Ni–Co–O System —This paper presents a topological analysis of phase equilibria in the Li2O–Al2O3–Ni–Co–O system. Using the fragmentary experimental data available, we construct isothermal phase diagrams of the Li2O–Al2O3–Nc–O (Nc = Ni + Co) and Li2O–Al2O3–NiO1 +x–CoO1 +x (0 ≤ x < 1) systems. Data are presented on phase equilibria involving Li(Ni,Co,Al)O2 (α-NaFeO2 structure), (Li,Ni,Co,Al)Al2O4 (spinel structure), (Li,Ni,Co)O (rock-salt structure), and (Li,Ni,Co)3O4 (spinel structure) solid solutions, whose homogeneity regions are evaluated. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Inorganic Materials Springer Journals

Phase Equilibria in the Li2O–Al2O3–Ni–Co–O System

Inorganic Materials , Volume 56 (8) – Aug 31, 2020

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References (50)

Publisher
Springer Journals
Copyright
Copyright © Pleiades Publishing, Ltd. 2020
ISSN
0020-1685
eISSN
1608-3172
DOI
10.1134/S0020168520070110
Publisher site
See Article on Publisher Site

Abstract

—This paper presents a topological analysis of phase equilibria in the Li2O–Al2O3–Ni–Co–O system. Using the fragmentary experimental data available, we construct isothermal phase diagrams of the Li2O–Al2O3–Nc–O (Nc = Ni + Co) and Li2O–Al2O3–NiO1 +x–CoO1 +x (0 ≤ x < 1) systems. Data are presented on phase equilibria involving Li(Ni,Co,Al)O2 (α-NaFeO2 structure), (Li,Ni,Co,Al)Al2O4 (spinel structure), (Li,Ni,Co)O (rock-salt structure), and (Li,Ni,Co)3O4 (spinel structure) solid solutions, whose homogeneity regions are evaluated.

Journal

Inorganic MaterialsSpringer Journals

Published: Aug 31, 2020

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