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J. Stewart (1989)
Optimization of parameters for semiempirical methods II. ApplicationsJournal of Computational Chemistry, 10
V. Smit, N. Zefirov, I. Bodrikov, M. Krimer (1979)
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Reactions of hexamethylphosphoramide with sulfur dichloride with the ambivalent participation of methylene chlorideDoklady Chemistry, 422
ISSN 00125008, Doklady Chemistry, 2011, Vol. 436, Part 1, pp. 1–4. © Pleiades Publishing, Ltd., 2011. Original Russian Text © I.V. Bodrikov, N.V. Nikitina, A.Yu. Subbotin, 2011, published in Doklady Akademii Nauk, 2011, Vol. 436, No. 1, pp. 54–57. CHEMISTRY Oxidative Dimerization of Sulfenyl Chlorides into Thiosulfonates under the Action of Hexamethylphosphoramide I. V. Bodrikov, N. V. Nikitina, and A. Yu. Subbotin Presented by Academician G.A. Abakumov June 29, 2010 Received July 5, 2010 DOI: 10.1134/S0012500811010010 Compounds containing electrophilic sulfur S(II) two alkyl groups that provides cascade processes involving solvent [5]. are mainly known as important reagents in alkene chemistry. Different aspects of reactions of sulfenyl We have found that HMPA (I) in the systems with chlorides, sulfur dichloride, and other S(II) reagents arenesulfenyl chlorides in methylene chloride pro with a wide range of unsaturated compounds, includ motes unsymmetrical oxidative dimerization of arene sulfenyl chlorides into thiosulfonates IIa and IIb. This ing linear and cyclic alkenes, alkynes, etc., are reaction includes the transfer of two oxygen atoms described in the literature [1, 2]. However, in spite of from HMPA molecules and the dimerization of sulfe the considerable synthetic and theoretical value of nyl chlorides. The same reaction takes place
Doklady Chemistry – Springer Journals
Published: Feb 6, 2011
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