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Nonclassical Conjugation in Organosilicon Polymers

Nonclassical Conjugation in Organosilicon Polymers Doklady Chemistry, Vol. 380, Nos. 1–3, 2001, pp. 247–251. Translated from Doklady Akademii Nauk, Vol. 380, No. 1, 2001, pp. 71–76. Original Russian Text Copyright © 2001 by Shamanin, Osadchev, Skorokhodov. CHEMISTRY V. V. Shamanin, A. Yu. Osadchev, and S. S. Skorokhodov Presented by Academician V. A. Kabanov March 12, 2001 Received February 9, 2001 Analysis of published experimental data led to the to the full occupancy of their valence shells. A different formulation of a hypothesis according to which (pÐd) situation is observed when the polymer backbone C s , p and (dÐd) homoconjugation is one of the main mech- atoms located closest to the atom under consideration s , p anisms of nonclassical electron density delocalization are able to undergo specific, other than van der Waals, in neutral or negatively charged forms of heteroorganic donor–acceptor b -interaction directly through space (in compounds. By combining regions of classical p -con- organic chemistry, this type of interaction is referred to jugation and/or lone electron pairs, homoconjugation in as homoconjugation). heteroorganic macromolecules can result in the forma- tion of common areas of “quasi-conjugation.” In terms of this concept, the existence of a new class of poly- D A meric systems, http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Doklady Chemistry Springer Journals

Nonclassical Conjugation in Organosilicon Polymers

Shamanin, V.; Osadchev, A.; Skorokhodov, S.
Doklady Chemistry , Volume 380 (3) – Oct 12, 2004
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References (5)

Publisher
Springer Journals
Copyright
Copyright © 2001 by MAIK “Nauka/Interperiodica”
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
0012-5008
eISSN
1608-3113
DOI
10.1023/A:1011994303228
Publisher site
See Article on Publisher Site

Abstract

Doklady Chemistry, Vol. 380, Nos. 1–3, 2001, pp. 247–251. Translated from Doklady Akademii Nauk, Vol. 380, No. 1, 2001, pp. 71–76. Original Russian Text Copyright © 2001 by Shamanin, Osadchev, Skorokhodov. CHEMISTRY V. V. Shamanin, A. Yu. Osadchev, and S. S. Skorokhodov Presented by Academician V. A. Kabanov March 12, 2001 Received February 9, 2001 Analysis of published experimental data led to the to the full occupancy of their valence shells. A different formulation of a hypothesis according to which (pÐd) situation is observed when the polymer backbone C s , p and (dÐd) homoconjugation is one of the main mech- atoms located closest to the atom under consideration s , p anisms of nonclassical electron density delocalization are able to undergo specific, other than van der Waals, in neutral or negatively charged forms of heteroorganic donor–acceptor b -interaction directly through space (in compounds. By combining regions of classical p -con- organic chemistry, this type of interaction is referred to jugation and/or lone electron pairs, homoconjugation in as homoconjugation). heteroorganic macromolecules can result in the forma- tion of common areas of “quasi-conjugation.” In terms of this concept, the existence of a new class of poly- D A meric systems,

Journal

Doklady Chemistry – Springer Journals

Published: Oct 12, 2004

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