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Nitration of Alkenes and Oxiranes with Nitrogen(IV) Oxide in Liquid and Supercritical Carbon Dioxide Media

Nitration of Alkenes and Oxiranes with Nitrogen(IV) Oxide in Liquid and Supercritical Carbon... For the first time the reactions of radical nitration of alkenes and oxiranes with nitrogen dioxide in the liquid and supercritical carbon dioxide (sc-CO2) media were carried out. Using octene-1, styrene, and their derivatives as examples, the effectiveness of the developed method for obtaining valuable 1,2-functionalized products, including nitroalcohols, dinitroalkanes, and nitronitrates have been shown. Due to the application of sc-CO2, the proposed method compares favorably with known analogs by the absence of by-products and waste organic solvents, as well as lesser fire and explosion hazards. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Doklady Chemistry Springer Journals

Nitration of Alkenes and Oxiranes with Nitrogen(IV) Oxide in Liquid and Supercritical Carbon Dioxide Media

Doklady Chemistry , Volume 500 (2) – Oct 1, 2021

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References (13)

Publisher
Springer Journals
Copyright
Copyright © Pleiades Publishing, Ltd. 2021. ISSN 0012-5008, Doklady Chemistry, 2021, Vol. 500, Part 2, pp. 209–212. © Pleiades Publishing, Ltd., 2021. Russian Text © The Author(s), 2021, published in Doklady Rossiiskoi Akademii Nauk. Khimiya, Nauki o Materialakh, 2021, Vol. 500, pp. 40–43.
ISSN
0012-5008
eISSN
1608-3113
DOI
10.1134/s0012500821100037
Publisher site
See Article on Publisher Site

Abstract

For the first time the reactions of radical nitration of alkenes and oxiranes with nitrogen dioxide in the liquid and supercritical carbon dioxide (sc-CO2) media were carried out. Using octene-1, styrene, and their derivatives as examples, the effectiveness of the developed method for obtaining valuable 1,2-functionalized products, including nitroalcohols, dinitroalkanes, and nitronitrates have been shown. Due to the application of sc-CO2, the proposed method compares favorably with known analogs by the absence of by-products and waste organic solvents, as well as lesser fire and explosion hazards.

Journal

Doklady ChemistrySpringer Journals

Published: Oct 1, 2021

Keywords: radical nitration; nitro compounds; supercritical carbon dioxide; nitrogen dioxide

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