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New rearrangements of phosphorus-nitrogen ligands

New rearrangements of phosphorus-nitrogen ligands ISSN 00125008, Doklady Chemistry, 2012, Vol. 445, Part 2, pp. 159–163. © Pleiades Publishing, Ltd., 2012. Original Russian Text © Yu.S. Panova, A.N. Kornev, V.V. Sushchev, A.V. Cherkasov, G.A. Abakumov, 2012, published in Doklady Akademii Nauk, 2012, Vol. 445, No. 5, pp. 533–537. CHEMISTRY New Rearrangements of Phosphorus–Nitrogen Ligands Yu. S. Panova, A. N. Kornev, V. V. Sushchev, A. V. Cherkasov, and Academician G. A. Abakumov Received April 5, 2012 DOI: 10.1134/S0012500812080058 The transformations in which trivalent phosphorus nient method for the synthesis of phosphinoamide, is converted to pentavalent fourcoordinate phosphorus phosphazenide, and iminophosphoranate complexes are thermodynamically very favorable. This enables of metals of different groups [3–5]. Recently, we many rearrangements in organic and organoelement found a new type of thermally initiated migration of the phosphinoamide group, [Ph PNPPh ], from the phosphorus compounds [1, 2]. The rearrangements of 2 2 mono, di, and triphosphinohydrazide ligands in hydrazide nitrogen to a quinolyl carbon atom the metal coordination sphere can serve as a conve (Scheme 1) [6]. PhMe, 130°C, 1 h N Ph P N NH N NH Ph P N Ph P 2 2 PPh Scheme 1. A study of the chemical properties of compound 1 The IR spectrum http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Doklady Chemistry Springer Journals

New rearrangements of phosphorus-nitrogen ligands

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References (13)

Publisher
Springer Journals
Copyright
Copyright © 2012 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
0012-5008
eISSN
1608-3113
DOI
10.1134/S0012500812080058
Publisher site
See Article on Publisher Site

Abstract

ISSN 00125008, Doklady Chemistry, 2012, Vol. 445, Part 2, pp. 159–163. © Pleiades Publishing, Ltd., 2012. Original Russian Text © Yu.S. Panova, A.N. Kornev, V.V. Sushchev, A.V. Cherkasov, G.A. Abakumov, 2012, published in Doklady Akademii Nauk, 2012, Vol. 445, No. 5, pp. 533–537. CHEMISTRY New Rearrangements of Phosphorus–Nitrogen Ligands Yu. S. Panova, A. N. Kornev, V. V. Sushchev, A. V. Cherkasov, and Academician G. A. Abakumov Received April 5, 2012 DOI: 10.1134/S0012500812080058 The transformations in which trivalent phosphorus nient method for the synthesis of phosphinoamide, is converted to pentavalent fourcoordinate phosphorus phosphazenide, and iminophosphoranate complexes are thermodynamically very favorable. This enables of metals of different groups [3–5]. Recently, we many rearrangements in organic and organoelement found a new type of thermally initiated migration of the phosphinoamide group, [Ph PNPPh ], from the phosphorus compounds [1, 2]. The rearrangements of 2 2 mono, di, and triphosphinohydrazide ligands in hydrazide nitrogen to a quinolyl carbon atom the metal coordination sphere can serve as a conve (Scheme 1) [6]. PhMe, 130°C, 1 h N Ph P N NH N NH Ph P N Ph P 2 2 PPh Scheme 1. A study of the chemical properties of compound 1 The IR spectrum

Journal

Doklady ChemistrySpringer Journals

Published: Sep 4, 2012

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