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New Reaction of Diphenyldichloromethane with Aprotic Dechloroalkoxylating Reagents

New Reaction of Diphenyldichloromethane with Aprotic Dechloroalkoxylating Reagents Doklady Chemistry, Vol. 395, Part 1, 2004, pp. 47–49. Translated from Doklady Akademii Nauk, Vol. 395, No. 3, 2004, pp. 353–355. Original Russian Text Copyright © 2004 by Gazizov, Ibragimov, Khamidullina, Karimova, Pudovik, Sadykova, Sinyashin. CHEMISTRY New Reaction of Diphenyldichloromethane with Aprotic Dechloroalkoxylating Reagents M. B. Gazizov, Sh. N. Ibragimov, O. D. Khamidullina, R. F. Karimova, M. A. Pudovik, R. R. Sadykova, and Corresponding Member of the RAS O. G. Sinyashin Received December 11, 2003 1 2 Methyl esters of P(IV) acids I and orthocarboxyl- R R P(O)(OMe) + Ph CCl 2 2 ates II show dechloroalkoxylating reactivity with (I)(III) 1 2 respect to organic compounds containing di- and Ph C(OMe)Cl + R R P(O)Cl, trichloromethyl groups [1, 2]. However, no information (IV) (V) is available on the application of compounds I and II in reactions with organic compounds containing a dichlo- IV Ph C=O + MeCl, romethylene group. Therefore, we studied reactions of (VI)(VII) diphenyldichloromethane III with compounds I and II. 1 2 1 2 () IV + () R R P(O)OP(O)R R + VII , In this work, we determined the structures of the (VIII) products and the general schemes of the reactions under study. () 3Ib http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Doklady Chemistry Springer Journals

New Reaction of Diphenyldichloromethane with Aprotic Dechloroalkoxylating Reagents

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References (1)

Publisher
Springer Journals
Copyright
Copyright © 2004 by MAIK “Nauka/Interperiodica”
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
0012-5008
eISSN
1608-3113
DOI
10.1023/B:DOCH.0000021274.72658.1e
Publisher site
See Article on Publisher Site

Abstract

Doklady Chemistry, Vol. 395, Part 1, 2004, pp. 47–49. Translated from Doklady Akademii Nauk, Vol. 395, No. 3, 2004, pp. 353–355. Original Russian Text Copyright © 2004 by Gazizov, Ibragimov, Khamidullina, Karimova, Pudovik, Sadykova, Sinyashin. CHEMISTRY New Reaction of Diphenyldichloromethane with Aprotic Dechloroalkoxylating Reagents M. B. Gazizov, Sh. N. Ibragimov, O. D. Khamidullina, R. F. Karimova, M. A. Pudovik, R. R. Sadykova, and Corresponding Member of the RAS O. G. Sinyashin Received December 11, 2003 1 2 Methyl esters of P(IV) acids I and orthocarboxyl- R R P(O)(OMe) + Ph CCl 2 2 ates II show dechloroalkoxylating reactivity with (I)(III) 1 2 respect to organic compounds containing di- and Ph C(OMe)Cl + R R P(O)Cl, trichloromethyl groups [1, 2]. However, no information (IV) (V) is available on the application of compounds I and II in reactions with organic compounds containing a dichlo- IV Ph C=O + MeCl, romethylene group. Therefore, we studied reactions of (VI)(VII) diphenyldichloromethane III with compounds I and II. 1 2 1 2 () IV + () R R P(O)OP(O)R R + VII , In this work, we determined the structures of the (VIII) products and the general schemes of the reactions under study. () 3Ib

Journal

Doklady Chemistry – Springer Journals

Published: Oct 18, 2004

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