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ISSN 00125008, Doklady Chemistry, 2009, Vol. 429, Part 2, pp. 305–310. © Pleiades Publishing, Ltd., 2009. Original Russian Text © I.I. Ponomarev, M.Yu. Zharinova, P.V. Petrovskii, Z.S. Klemenkova, 2009, published in Doklady Akademii Nauk, 2009, Vol. 429, No. 4, pp. 490–495. CHEMISTRY New Poly(1,2,3triazolesulfonic acids) for Proton Exchange Membranes of Fuel Cell I. I. Ponomarev, M. Yu. Zharinova, P. V. Petrovskii, and Z. S. Klemenkova Presented by Academician A.R. Khokhlov May 29, 2009 Received June 3, 2009 DOI: 10.1134/S0012500809120027 Fuel cells (FCs) based on proton exchange mem disulfonic acid, hydroquinone, 4,4'isopropylidene branes are promising as electric power sources. They diphenol, cyanuric chloride, metanilic acid, sodium provide a possibility to receive energy from hydrogen, hydroxide from Acrus were used without additional synthetic or biosynthetic fuel and can operate with purification. higher efficiency as compared with heat engines [1, 2]. 1,3,5Triethinylbenzene (6) from Alfa Aesar and Hydrated sulfonicacid polymerelectrolyte pro 2,2'benzidinedisulfonic acid from Kodak were also ton exchange membrane (PEM) in an FC provides a used without additional purification. transfer of protons resulting from electrochemical oxi H NMR spectra of studied compounds were dation of fuel on anode to cathode and separates TM recorded on a Bruker Avance 400 spectrometer anode
Doklady Chemistry – Springer Journals
Published: Dec 23, 2009
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