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New Photochromic Spiropyrans with ortho-Hydroxyaldimine Substituent

New Photochromic Spiropyrans with ortho-Hydroxyaldimine Substituent A series of new spiropyrans of indoline series with ortho-hydroxyaldimine substituent has been synthesized, their structure and photochromic properties have been studied. The structure of the obtained compounds was confirmed by the data of 1H NMR and IR spectroscopy and elemental analysis. Photochromic properties of the prepared compounds have been studied. The introduction of ortho-hydroxy group into aldimine fragment of molecule (in the 6 position of the 2H-chromene fragment) has increased the lifetime of merocyanine isomer by 40 times as compared with amino-substituted spiropyran. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Doklady Chemistry Springer Journals

New Photochromic Spiropyrans with ortho-Hydroxyaldimine Substituent

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References (9)

Publisher
Springer Journals
Copyright
Copyright © 2018 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
0012-5008
eISSN
1608-3113
DOI
10.1134/S001250081810004X
Publisher site
See Article on Publisher Site

Abstract

A series of new spiropyrans of indoline series with ortho-hydroxyaldimine substituent has been synthesized, their structure and photochromic properties have been studied. The structure of the obtained compounds was confirmed by the data of 1H NMR and IR spectroscopy and elemental analysis. Photochromic properties of the prepared compounds have been studied. The introduction of ortho-hydroxy group into aldimine fragment of molecule (in the 6 position of the 2H-chromene fragment) has increased the lifetime of merocyanine isomer by 40 times as compared with amino-substituted spiropyran.

Journal

Doklady ChemistrySpringer Journals

Published: Nov 5, 2018

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