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Nanocomposites in the Ru2+ Organic Complex–SiO2 System as a New Class of Metal–Polymer Complexes

Nanocomposites in the Ru2+ Organic Complex–SiO2 System as a New Class of Metal–Polymer Complexes Doklady Chemistry, Vol. 394, Part 2, 2004, pp. 31–33. Translated from Doklady Akademii Nauk, Vol. 394, No. 5, 2004, pp. 636–638. Original Russian Text Copyright © 2004 by Khimich, Semov, Chepik. CHEMISTRY 2+ Nanocomposites in the Ru Organic Complex–SiO System as a New Class of Metal–Polymer Complexes N. N. Khimich, M. P. Semov, and L. F. Chepik Presented by Academician V.Ya. Shevchenko July 22, 2003 Received August 11, 2003 Organic complexes of some transition metal ions sol–gel process yields a hybrid through intermolecular + 2+ 2+ 2+ 2+ (Cu , Cd , Pt , Ru , and others) have fairly interest- binding of the organic ([RuL ] ) and inorganic (SiO ) 3 2 ing photochemical and electrochemical properties. components [6–8]. This intermolecular binding is due 2+ Complexes of the [RuL ] type containing to van der Waals and hydrophobic–hydrophilic interac- 2,2'-bipyridyl and related structures as ligands possess tions of the components and, hence, is rather weak [9]. 2+ a unique combination of these properties and high Therefore, the [RuL ] complex is weakly held in the thermal and chemical stabilities [1]. The prospects for SiO matrix, and the physical and mechanical proper- using ruthenium complexes for the solution http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Doklady Chemistry Springer Journals

Nanocomposites in the Ru2+ Organic Complex–SiO2 System as a New Class of Metal–Polymer Complexes

Doklady Chemistry , Volume 394 (6) – Oct 18, 2004

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References (1)

Publisher
Springer Journals
Copyright
Copyright © 2004 by MAIK “Nauka/Interperiodica”
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
0012-5008
eISSN
1608-3113
DOI
10.1023/B:DOCH.0000017271.99432.f2
Publisher site
See Article on Publisher Site

Abstract

Doklady Chemistry, Vol. 394, Part 2, 2004, pp. 31–33. Translated from Doklady Akademii Nauk, Vol. 394, No. 5, 2004, pp. 636–638. Original Russian Text Copyright © 2004 by Khimich, Semov, Chepik. CHEMISTRY 2+ Nanocomposites in the Ru Organic Complex–SiO System as a New Class of Metal–Polymer Complexes N. N. Khimich, M. P. Semov, and L. F. Chepik Presented by Academician V.Ya. Shevchenko July 22, 2003 Received August 11, 2003 Organic complexes of some transition metal ions sol–gel process yields a hybrid through intermolecular + 2+ 2+ 2+ 2+ (Cu , Cd , Pt , Ru , and others) have fairly interest- binding of the organic ([RuL ] ) and inorganic (SiO ) 3 2 ing photochemical and electrochemical properties. components [6–8]. This intermolecular binding is due 2+ Complexes of the [RuL ] type containing to van der Waals and hydrophobic–hydrophilic interac- 2,2'-bipyridyl and related structures as ligands possess tions of the components and, hence, is rather weak [9]. 2+ a unique combination of these properties and high Therefore, the [RuL ] complex is weakly held in the thermal and chemical stabilities [1]. The prospects for SiO matrix, and the physical and mechanical proper- using ruthenium complexes for the solution

Journal

Doklady ChemistrySpringer Journals

Published: Oct 18, 2004

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