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E. Seddon, K. Seddon (1984)
The Chemistry of ruthenium
Doklady Chemistry, Vol. 394, Part 2, 2004, pp. 31–33. Translated from Doklady Akademii Nauk, Vol. 394, No. 5, 2004, pp. 636–638. Original Russian Text Copyright © 2004 by Khimich, Semov, Chepik. CHEMISTRY 2+ Nanocomposites in the Ru Organic Complex–SiO System as a New Class of Metal–Polymer Complexes N. N. Khimich, M. P. Semov, and L. F. Chepik Presented by Academician V.Ya. Shevchenko July 22, 2003 Received August 11, 2003 Organic complexes of some transition metal ions sol–gel process yields a hybrid through intermolecular + 2+ 2+ 2+ 2+ (Cu , Cd , Pt , Ru , and others) have fairly interest- binding of the organic ([RuL ] ) and inorganic (SiO ) 3 2 ing photochemical and electrochemical properties. components [6–8]. This intermolecular binding is due 2+ Complexes of the [RuL ] type containing to van der Waals and hydrophobic–hydrophilic interac- 2,2'-bipyridyl and related structures as ligands possess tions of the components and, hence, is rather weak [9]. 2+ a unique combination of these properties and high Therefore, the [RuL ] complex is weakly held in the thermal and chemical stabilities [1]. The prospects for SiO matrix, and the physical and mechanical proper- using ruthenium complexes for the solution
Doklady Chemistry – Springer Journals
Published: Oct 18, 2004
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