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T. Smith, J. Pilbrow (1974)
The determination of structural properties of dimeric transition metal ion complexes from epr spectraCoordination Chemistry Reviews, 13
G. Larin, V. Shul’gin, E. Sarnit (1999)
Weak long-range spin–spin exchange interactions in a copper(II) complexMendeleev Communications, 9
G. Larin, V. Shul’gin, A. Gusev, A. Chernega (2003)
Structure and EPR Spectrum of the Binuclear Copper(II) Complex with 2-Hydroxypropiophenone AdipoyldihydrazoneDoklady Chemistry, 390
ISSN 0012-5008, Doklady Chemistry, 2007, Vol. 414, Part 1, pp. 115–119. © Pleiades Publishing, Ltd., 2007. Original Russian Text © G.M. Larin, A.N. Gusev, Yu.V. Trush, V.F. Shul’gin, G.G. Aleksandrov, I.L. Eremenko, 2007, published in Doklady Akademii Nauk, 2007, Vol. 414, No. 2, pp. 194–198. CHEMISTRY Molecular and Crystal Structures of Binuclear Copper(II) Complexes with Acylhydrazones of Benzenedicarboxylic Acids a b b b G. M. Larin , A. N. Gusev , Yu. V. Trush , V. F. Shul’gin , a a G. G. Aleksandrov , and Academician I. L. Eremenko Received October 24, 2006 DOI: 10.1134/S0012500807050047 Recently, we described three series of binuclear copper(II) complexes based on acetylhydrazones of β- diketones (I) [1–6], salicylaldehyde (II) [7–9], and ali- N NH phatic-aromatic ketones (III) [10–14]. OH HO A specific feature of the molecular structure of com- O HN N plexes I–III is the presence of a –(CH) – aliphatic bridge (spacer) connecting the coordination polyhedra 2 4 of two tridentate copper chelates; hence, these com- H L , X = H; H L , X = CH 4 4 3 plexes can be classified as spacered dimers. According to X-ray diffraction [7, 8, 12, 13], the distance between the copper
Doklady Chemistry – Springer Journals
Published: May 24, 2007
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