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A metal-free catalyzed oxidation of 2-nitro-4-methylsulfonatotoluene(NMST) to produce 2-nitro-4-methylsulfonatobenzoic acid(NMSBA) under Taylor flow regimes is introduced. N,N′,N″- trihydroxyisocyanuric acid (THICA) as the catalyst and nitric acid as promoter, molecular oxygen as oxidant. The related parameters, such as residence time (τ), reaction temperature (T), and molar flow ratio of oxygen/substrate were investigated systematically. A good yield and selectivity were obtained by taking advantages of continuous flow system. Compared with the traditional batch oxidation process, the new continuous process is more safe and environmentally friendly.Graphical abstract[graphic not available: see fulltext]
Journal of Flow Chemistry – Springer Journals
Published: Dec 1, 2022
Keywords: Continuous-flow; Metal-free catalyzed oxidation; Molecular oxygen; 2-nitro-4-methylsulfonylbenzoic acid
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