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“Matrix” Stabilization of RhVIIons in the Structure of MIIEVIO4(E = Cr, Mo, W)

“Matrix” Stabilization of RhVIIons in the Structure of MIIEVIO4(E = Cr, Mo, W) Doklady Chemistry, Vol. 379, Nos. 4–6, 2001, pp. 209–211. Translated from Doklady Akademii Nauk, Vol. 379, No. 4, 2001, pp. 494–496. Original Russian Text Copyright © 2001 by Dolzhenko, Avdei, Evtushenko, Mukhanov, Komozin, Kiselev. CHEMISTRY VI “Matrix” Stabilization of Rh Ions in the Structure II VI of M E O (E = Cr, Mo, W) V. D. Dolzhenko, A. V. Avdei, E. G. Evtushenko, V. A. Mukhanov, P. N. Komozin, and Yu. M. Kiselev Presented by Academician Yu.D. Tret’yakov March 21, 2001 Received April 2, 2001 Great interest in the problem of the stability of plat- [8, 9]. The chromium content was determined by titra- inum-metal ions in the highest oxidation states has been tion. stimulated by recent quantum-chemical calculations of Complex I was synthesized as described elsewhere tetrahedral oxo complexes [1–3]. These calculations + – – [4]; hypobromite ions were used as an oxidant. The for- predict that even the Ir O , Ir O , and Rh O ions in 4 4 4 mation of the complex was monitored by EPR (a which the oxidation state of the metal is +9, +7, and +7, Radiopan SE/X-2544 radiospectrometer, 77 K, glassy respectively, are thermodynamically probable. The matrix, X-band, http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Doklady Chemistry Springer Journals

“Matrix” Stabilization of RhVIIons in the Structure of MIIEVIO4(E = Cr, Mo, W)

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References (1)

Publisher
Springer Journals
Copyright
Copyright © 2001 by MAIK “Nauka/Interperiodica”
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
0012-5008
eISSN
1608-3113
DOI
10.1023/A:1011695718925
Publisher site
See Article on Publisher Site

Abstract

Doklady Chemistry, Vol. 379, Nos. 4–6, 2001, pp. 209–211. Translated from Doklady Akademii Nauk, Vol. 379, No. 4, 2001, pp. 494–496. Original Russian Text Copyright © 2001 by Dolzhenko, Avdei, Evtushenko, Mukhanov, Komozin, Kiselev. CHEMISTRY VI “Matrix” Stabilization of Rh Ions in the Structure II VI of M E O (E = Cr, Mo, W) V. D. Dolzhenko, A. V. Avdei, E. G. Evtushenko, V. A. Mukhanov, P. N. Komozin, and Yu. M. Kiselev Presented by Academician Yu.D. Tret’yakov March 21, 2001 Received April 2, 2001 Great interest in the problem of the stability of plat- [8, 9]. The chromium content was determined by titra- inum-metal ions in the highest oxidation states has been tion. stimulated by recent quantum-chemical calculations of Complex I was synthesized as described elsewhere tetrahedral oxo complexes [1–3]. These calculations + – – [4]; hypobromite ions were used as an oxidant. The for- predict that even the Ir O , Ir O , and Rh O ions in 4 4 4 mation of the complex was monitored by EPR (a which the oxidation state of the metal is +9, +7, and +7, Radiopan SE/X-2544 radiospectrometer, 77 K, glassy respectively, are thermodynamically probable. The matrix, X-band,

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Doklady Chemistry – Springer Journals

Published: Oct 12, 2004

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