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- Publisher
- Springer Journals
- Copyright
- Copyright © 2019 by Springer-Verlag GmbH Germany, part of Springer Nature
- Subject
- Chemistry; Electrochemistry; Renewable and Green Energy; Optical and Electronic Materials; Condensed Matter Physics; Energy Storage
- ISSN
- 0947-7047
- eISSN
- 1862-0760
- DOI
- 10.1007/s11581-019-02932-7
- Publisher site
- See Article on Publisher Site
Abstract
Metal sulfides possess great potential for high-performance rechargeable lithium-ion batteries (LIBs). In this work, Bi2S3 with a lemongrass-like morphology was successfully synthesized via a facile solvothermal growth, followed by subsequent calcination. When employed as an anode material in lithium-ion batteries, the Bi2S3 showed a high reversible capacity, a better cycling stability, and a superior rate performance. A reversible capacity of 686 mAh g−1 was obtained at a current density of 200 mA g−1 after 150 cycles. When the current density was increased to 2000 mA g−1, Bi2S3 could deliver a capacity of more than 400 mAh g−1 after 500 cycles. This excellent electrochemical performance could be attributed to the featured structure of lemongrass-like Bi2S3, which can accommodate volume changes, shorten the ionic diffusion path, and enlarge the material/electrolyte contact area.
Journal
Ionics – Springer Journals
Published: Mar 6, 2019