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Layered Hydrogen Peroxide Intercalates

Layered Hydrogen Peroxide Intercalates Doklady Chemistry, Vol. 377, Nos. 1–3, 2001, pp. 69–70. Translated from Doklady Akademii Nauk, Vol. 377, No. 1, 2001, pp. 62–63. Original Russian Text Copyright © 2001 by Tripol’skaya, Pilipenko, Pokhabova, Ippolitov. CHEMISTRY T. A. Tripol’skaya, G. P. Pilipenko, I. V. Pokhabova, and Corresponding Member of the RAS E. G. Ippolitov Received November 9, 2000 We have shown previously [1–3] that hydroxide The initial DLAH was obtained by the procedure ligands in the coordination sphere of a central ion can described elsewhere [7]. In solids, lithium was deter- be replaced by hydroperoxide ligands in concentrated mined by flame photometry, the aluminum content was hydrogen peroxide solutions. Using this approach, we found complexometrically, the water content was developed an efficient method for obtaining stable per- derived from weight losses at 500¡‘, and the content of oxide complexes of some main-group metals (for hydrogen peroxide was found by titration with perman- example, B, Al, Sn, Sb, In). The outer-sphere cations in ganate [8–10]. these compounds were Na, K, Ca, or Ba. Solid DLAH was reacted either with hydrogen per- oxide solutions or with hydrogen peroxide vapor. In this study, we extended this approach to the syn- thesis of peroxides of other http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Doklady Chemistry Springer Journals

Layered Hydrogen Peroxide Intercalates

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References (4)

Publisher
Springer Journals
Copyright
Copyright © 2001 by MAIK “Nauka/Interperiodica”
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
0012-5008
eISSN
1608-3113
DOI
10.1023/A:1018808223405
Publisher site
See Article on Publisher Site

Abstract

Doklady Chemistry, Vol. 377, Nos. 1–3, 2001, pp. 69–70. Translated from Doklady Akademii Nauk, Vol. 377, No. 1, 2001, pp. 62–63. Original Russian Text Copyright © 2001 by Tripol’skaya, Pilipenko, Pokhabova, Ippolitov. CHEMISTRY T. A. Tripol’skaya, G. P. Pilipenko, I. V. Pokhabova, and Corresponding Member of the RAS E. G. Ippolitov Received November 9, 2000 We have shown previously [1–3] that hydroxide The initial DLAH was obtained by the procedure ligands in the coordination sphere of a central ion can described elsewhere [7]. In solids, lithium was deter- be replaced by hydroperoxide ligands in concentrated mined by flame photometry, the aluminum content was hydrogen peroxide solutions. Using this approach, we found complexometrically, the water content was developed an efficient method for obtaining stable per- derived from weight losses at 500¡‘, and the content of oxide complexes of some main-group metals (for hydrogen peroxide was found by titration with perman- example, B, Al, Sn, Sb, In). The outer-sphere cations in ganate [8–10]. these compounds were Na, K, Ca, or Ba. Solid DLAH was reacted either with hydrogen per- oxide solutions or with hydrogen peroxide vapor. In this study, we extended this approach to the syn- thesis of peroxides of other

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Doklady Chemistry – Springer Journals

Published: Oct 12, 2004

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