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Ola Karlsson, J. Stubbs, Robert Carrier, D. Sundberg (2003)
Dynamic Modeling of Non‐equilibrium Latex Particle Morphology Development During Seeded Emulsion PolymerizationPolymer Reaction Engineering, 11
V. Kislenko (1999)
Emulsion graft polymerization: mechanism of formation of dispersionsColloids and Surfaces A: Physicochemical and Engineering Aspects, 152
F. Heatley, P. Lovell, Tsuyoshi Yamashita (1998)
Chain transfer to polymer in free-radical solution polymerization of 2-ethylhexyl acrylate studied by NMR spectroscopyMacromolecules, 31
Mukul Jain, R. Vora, U. Satpathy (2003)
Kinetics of emulsion copolymerization of methylmethacrylate and ethylacrylate: effect of type and concentration of initiator in unseeded polymerization systemEuropean Polymer Journal, 39
O. Karlsson, H. Hassander, B. Wesslén (2000)
Influence of seed polymer molecular weight on polymerization kinetics and particle morphology of structured styrene–butadiene latexesJournal of Applied Polymer Science, 77
Yoon Kim, Y. Choi, A. Wang, I. Chung (2002)
Synthesis of Exfoliated PS/Na−MMT Nanocomposites via Emulsion PolymerizationChemistry of Materials, 14
Tae Kim, Lee Jang, D. Lee, H. Choi, M. Jhon (2002)
Synthesis and rheology of intercalated polystyrene/Na+-montmorillonite nanocompositesMacromolecular Rapid Communications, 23
Jan‐Erik Jönsson, O. Karlsson, H. Hassander, B. Törnell (2007)
Semi-continuous emulsion polymerization of styrene in the presence of poly(methyl methacrylate) seed particles. Polymerization conditions giving core–shell particlesEuropean Polymer Journal, 43
C. Winzor, D. Sundberg (1992)
Conversion dependent morphology predictions for composite emulsion polymers: 1. Synthetic laticesPolymer, 33
I. Maxwell, B. Morrison, D. Napper, R. Gilbert (1991)
ENTRY OF FREE RADICALS INTO LATEX PARTICLES IN EMULSION POLYMERIZATIONMacromolecules, 24
Lourdes Arbina, L. Gugliotta, M. Barandiaran, J. Asua (1998)
Effect of oxygen on emulsion polymerisation kinetics: a study by reaction calorimetryPolymer, 39
Xiuli Cheng, Zhengxian Chen, T. Shi, Hongyan Wang (2007)
Synthesis and characterization of core-shell LIPN-fluorine-containing polyacrylate latexColloids and Surfaces A: Physicochemical and Engineering Aspects, 292
F. Healtey N. M. Ahmad (1998)
10.1021/ma971283rMacromolecules, 31
C. Chern, Jiang-Jen Lin, Yanting Lin, Shu-zhen Lai (2006)
Kinetics of styrene emulsion polymerization in the presence of montmorilloniteEuropean Polymer Journal, 42
L. Karlsson, O. Karlsson, D. Sundberg (2003)
Nonequilibrium particle morphology development in seeded emulsion polymerization. II. Influence of seed polymer TgJournal of Applied Polymer Science, 90
J. Stubbs, O. Karlsson, Janniz Jönsson, E. Sundberg, Y. Durant, D. Sundberg (1999)
Non-equilibrium particle morphology development in seeded emulsion polymerization. 1: penetration of monomer and radicals as a function of monomer feed rate during second stage polymerizationColloids and Surfaces A: Physicochemical and Engineering Aspects, 153
O. Karlsson, H. Hassander, B. Wesslén (1997)
Morphology of poly(isoprene-co-styrene-co-methacrylic acid) latex prepared by two-stage seeded emulsion polymerizationJournal of Applied Polymer Science, 63
Y. Choi, M. Choi, Kihyun Wang, S. Kim, Yoon Kim, I. Chung (2001)
Synthesis of exfoliated PMMA/Na-MMT nanocomposites via soap-free emulsion polymerizationMacromolecules, 34
Jan‐Erik Jönsson, O. Karlsson, H. Hassander, B. Törnell (2001)
Shell-layer stability in core-shell particles prepared with different initiatorsMacromolecules, 34
Sharon Lee, A. Rudin (1992)
Synthesis of core-shell latexes by redox initiation at ambient temperaturesJournal of Polymer Science Part A, 30
Y. Choi, Kihyun Wang, A. Xu, I. Chung (2002)
Synthesis of exfoliated polyacrylonitrile/Na-MMT nanocomposites via emulsion polymerizationChemistry of Materials, 14
S. Arora, R. Gesthuisen, S. Engell (2007)
Model based operation of emulsion polymerization reactors with evaporative cooling: Application to vinyl acetate homopolymerizationComput. Chem. Eng., 31
J. Joensson, H. Hassander, Bertil Toernell (1994)
Polymerization Conditions and the Development of a Core-Shell Morphology in PMMA/PS Latex Particles. 1. Influence of Initiator Properties and Mode of Monomer AdditionMacromolecules, 27
B. Kim, J. Jung, S. Hong, J. Joo, A. Epstein, K. Mizoguchi, J. Kim, H. Choi (2002)
Nanocomposite of Polyaniline and Na+-Montmorillonite ClayMacromolecules, 35
Abstract Poly(n-butyl methacrylate)/poly(methyl methacrylate) polymer networks were synthesized by two-step emulsion polymerization with sodium dodecylsulfonate and polyoxyethylene nonylphenolether as the emulsifier, distilled water as the continuous medium, and potassium persulfate as the initiator. The kinetics of two-step emulsion polymerization was studied. Effects of emulsifier concentration, initiator concentration, and polymerization temperature on monomer conversion and polymerization rate were investigated in detail. Experimental data indicate that both the steady state polymerization rate and monomer conversion increase with the augment of emulsifier concentration, initiator concentration, or reaction temperature.
Fibers and Polymers – Springer Journals
Published: Apr 1, 2008
Keywords: Polymer Sciences
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