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Isomerization [trans-B20H18]2– → [iso-B20H18]2– during silver(I) complexation with triphenylphosphine

Isomerization [trans-B20H18]2– → [iso-B20H18]2– during silver(I) complexation with... The trans–iso isomerization of the dimeric borohydride cluster anion [B20H18]2– in the course of the silver(I) complexation reaction with triphenylphosphine has been described for the first time. The isomeric complexes [Ag2(Ph3P)6[trans-B20H18]] and [Ag2(Ph3P)6[iso-B20H18]] have been isolated and characterized by physicochemical methods. The structures of the compounds have been determined by X-ray crystallography. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Doklady Chemistry Springer Journals

Isomerization [trans-B20H18]2– → [iso-B20H18]2– during silver(I) complexation with triphenylphosphine

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References (9)

Publisher
Springer Journals
Copyright
Copyright © 2015 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
0012-5008
eISSN
1608-3113
DOI
10.1134/S0012500815120046
Publisher site
See Article on Publisher Site

Abstract

The trans–iso isomerization of the dimeric borohydride cluster anion [B20H18]2– in the course of the silver(I) complexation reaction with triphenylphosphine has been described for the first time. The isomeric complexes [Ag2(Ph3P)6[trans-B20H18]] and [Ag2(Ph3P)6[iso-B20H18]] have been isolated and characterized by physicochemical methods. The structures of the compounds have been determined by X-ray crystallography.

Journal

Doklady ChemistrySpringer Journals

Published: Jan 5, 2016

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