Access the full text.
Sign up today, get DeepDyve free for 14 days.
D. Moosbauer, Sandra Zugmann, M. Amereller, H. Gores (2010)
Effect of Ionic Liquids as Additives on Lithium Electrolytes: Conductivity, Electrochemical Stability, and Aluminum Corrosion†Journal of Chemical & Engineering Data, 55
P. Snedden, A. Cooper, K. Scott, N. Winterton (2003)
Cross-Linked Polymer-Ionic Liquid Composite MaterialsMacromolecules, 36
J. Coates (2006)
Interpretation of Infrared Spectra, A Practical Approach
Alvárez, Alegría, Colmenero (1993)
Interconnection between frequency-domain Havriliak-Negami and time-domain Kohlrausch-Williams-Watts relaxation functions.Physical review. B, Condensed matter, 47 1
Y. Kumar, S. Hashmi, G. Pandey (2011)
Lithium ion transport and ion–polymer interaction in PEO based polymer electrolyte plasticized with ionic liquidSolid State Ionics, 201
R. Sengwa, Sonu Sankhla (2007)
Dielectric dispersion study of coexisting phases of aqueous polymeric solution : Poly(vinyl alcohol) + poly(vinyl pyrrolidone) two-phase systemsPolymer, 48
R. Ando, L. Siqueira, Fernanda Bazito, R. Torresi, P. Santos (2007)
The sulfur dioxide-1-butyl-3-methylimidazolium bromide interaction: drastic changes in structural and physical properties.The journal of physical chemistry. B, 111 30
Bo Yu, Feng Zhou, Chengwei Wang, Wei-min Liu (2007)
A novel gel polymer electrolyte based on poly ionic liquid 1-ethyl 3-(2-methacryloyloxy ethyl) imidazolium iodideEuropean Polymer Journal, 43
S. Sekhon, D. Kaur, Jin-Soo Park, Koji Yamada (2012)
Ion transport properties of ionic liquid based gel electrolytesElectrochimica Acta, 60
J. Tarascon, M. Armand (2001)
Issues and challenges facing rechargeable lithium batteriesNature, 414
G. Pandey, S. Hashmi (2009)
Experimental investigations of an ionic-liquid-based, magnesium ion conducting, polymer gel electrolyteJournal of Power Sources, 187
Changyong Park, Dong‐Won Kim, J. Prakash, Yang‐Kook Sun (2003)
Electrochemical stability and conductivity enhancement of composite polymer electrolytesSolid State Ionics, 159
H. Tokuda, K. Ishii, M. Susan, S. Tsuzuki, K. Hayamizu, M. Watanabe (2004)
Physicochemical Properties and Structures of Room Temperature Ionic Liquids. 1. Variation of Anionic SpeciesJournal of Physical Chemistry B, 110
L. Priya, J. Jog (2002)
Poly(vinylidene fluoride)/clay nanocomposites prepared by melt intercalation: Crystallization and dynamic mechanical behavior studiesJournal of Polymer Science Part B, 40
D. Fragiadakis, S. Dou, R. Colby, J. Runt (2008)
Molecular Mobility, Ion Mobility, and Mobile Ion Concentration in Poly(ethylene oxide)-Based Polyurethane IonomersMacromolecules, 41
H. Kataoka, and Saito, T. Sakai, Eliana and, P. Mustarelli (2000)
Conduction Mechanisms of PVDF-Type Gel Polymer Electrolytes of Lithium Prepared by a Phase Inversion ProcessJournal of Physical Chemistry B, 104
D. Kaur, K. Yamada, Jin-Soo Park, S. Sekhon (2009)
Correlation between ion diffusional motion and ionic conductivity for different electrolytes based on ionic liquid.The journal of physical chemistry. B, 113 16
Megan Hoarfrost, R. Segalman (2010)
Ionic Conductivity of Nanostructured Block Copolymer/Ionic Liquid MembranesMacromolecules, 44
Dixon (1990)
Specific-heat spectroscopy and dielectric susceptibility measurements of salol at the glass transition.Physical review. B, Condensed matter, 42 13
Hu Cheng, Changbao Zhu, Bing Huang, Mi Lu, Yong Yang (2007)
Synthesis and electrochemical characterization of PEO-based polymer electrolytes with room temperature ionic liquidsElectrochimica Acta, 52
K. Funke (1993)
Jump relaxation in solid electrolytesProgress in Solid State Chemistry, 22
R. Böhmer, C. Angell (1992)
Correlations of the nonexponentiality and state dependence of mechanical relaxations with bond connectivity in Ge-As-Se supercooled liquids.Physical review. B, Condensed matter, 45 17
R. Carlin, H. Long, J. Fuller, P. Trulove (1994)
Dual Intercalating Molten Electrolyte BatteriesJournal of The Electrochemical Society, 141
R. Klein, Shihai Zhang, S. Dou, Brad Jones, R. Colby, J. Runt (2006)
Modeling electrode polarization in dielectric spectroscopy: Ion mobility and mobile ion concentration of single-ion polymer electrolytes.The Journal of chemical physics, 124 14
E. Morales, J. Acosta (1999)
Synthesis and characterisation of poly(methylalkoxysiloxane) solid polymer electrolytes incorporating different lithium saltsElectrochimica Acta, 45
F. Croce, S. Panero, S. Passerini, B. Scrosati (1994)
The role of conductive polymers in advanced electrochemical technologyElectrochimica Acta, 39
J. Dyre, T. Schrøder (2000)
Universality of ac conduction in disordered solidsReviews of Modern Physics, 72
Akihiro Noda, and Hayamizu, M. Watanabe (2001)
Pulsed-Gradient Spin−Echo 1H and 19F NMR Ionic Diffusion Coefficient, Viscosity, and Ionic Conductivity of Non-Chloroaluminate Room-Temperature Ionic LiquidsJournal of Physical Chemistry B, 105
A. Stephan (2006)
Review on gel polymer electrolytes for lithium batteriesEuropean Polymer Journal, 42
E. Giannelis (1996)
Polymer Layered Silicate NanocompositesAdvanced Materials, 8
A. Saroj, R. Singh (2012)
Thermal, dielectric and conductivity studies on PVA/Ionic liquid [EMIM][EtSO4] based polymer electrolytesJournal of Physics and Chemistry of Solids, 73
F. Groce, F. Gerace, G. Dautzemberg, S. Passerini, G. Appetecchi, B. Scrosati (1994)
SYNTHESIS AND CHARACTERIZATION OF HIGHLY CONDUCTING GEL ELECTROLYTESElectrochimica Acta, 39
J. Fuller, A. Breda, R. Carlin (1997)
Ionic Liquid‐Polymer Gel ElectrolytesJournal of The Electrochemical Society, 144
A. Patil, A. Heeger, F. Wudl (1988)
Optical properties of conducting polymersChemical Reviews, 88
S. Seki, Takeshi Kobayashi, Nobuyuki Serizawa, Yo Kobayashi, K. Takei, H. Miyashiro, K. Hayamizu, S. Tsuzuki, T. Mitsugi, Y. Umebayashi, M. Watanabe (2010)
Electrolyte properties of 1-alkyl-2,3,5-trimethylpyrazolium cation-based room-temperature ionic liquids for lithium secondary batteriesJournal of Power Sources, 195
(2003)
Macromole- cules 36:4549
M. Kroon, W. Buijs, C. Peters, G. Witkamp (2007)
Quantum chemical aided prediction of the thermal decomposition mechanisms and temperatures of ionic liquidsThermochimica Acta, 465
S. Chaurasia, R. Singh, S. Chandra (2011)
Structural and transport studies on polymeric membranes of PEO containing ionic liquid, EMIM-TY: Evidence of complexationSolid State Ionics, 183
Boor Singh, S. Sekhon (2005)
Polymer electrolytes based on room temperature ionic liquid: 2,3-dimethyl-1-octylimidazolium triflate.The journal of physical chemistry. B, 109 34
M. Susan, Taketo Kaneko, Akihiro Noda, M. Watanabe (2005)
Ion gels prepared by in situ radical polymerization of vinyl monomers in an ionic liquid and their characterization as polymer electrolytes.Journal of the American Chemical Society, 127 13
H.J Walls, Jian Zhou, Jeffrey Yerian, P. Fedkiw, Saad Khan, Micah Stowe, Gregory Baker (2000)
Fumed silica-based composite polymer electrolytes: synthesis, rheology, and electrochemistryJournal of Power Sources, 89
S. Chen, Chien‐Shiun Liao (1993)
Conductivity relaxation and chain motions in conjugated conducting polymers: neutral poly(3-alkylthiophenes)Macromolecules, 26
N. Park, Y. Bae (2010)
Electrochemical properties for ionic liquid/polymer electrolyte systemsJournal of Polymer Science Part B, 48
Ionic conductivity and transport properties of polyvinylidenefluoride–co-hexafluoropropylene– montmorillonite intercalated nanocomposite electrolytes based on ionic liquid 1-butyl-3-methylimidazolium bromide have been studied for various concentrations of montmorillonite clay. Ionic conductivity of the order of 10−3 S cm−1 at room temperature with thermal stability up to about 235 °C has been obtained for the electrolyte system. The electrolyte system has superior properties at 5 wt% of clay loading with highly amorphous morphology as seen from selected area electron diffraction micrograph. Scanning electron microscope studies show that the electrolyte system has highly porous morphology and the ionic liquid is trapped in the pores. Dielectric properties of the electrolyte system have been studied to investigate the relaxation processes occurring in the system. Variation of real part of dielectric permittivity with frequency shows two relaxation processes occurring in the system, slow at low frequency and fast at high frequency. Kohlrausch exponential parameter has been calculated from modulus formalism, and the values show that the distribution of conductivity relaxation times becomes narrower with increasing clay loading.
Ionics – Springer Journals
Published: Mar 10, 2013
Read and print from thousands of top scholarly journals.
Already have an account? Log in
Bookmark this article. You can see your Bookmarks on your DeepDyve Library.
To save an article, log in first, or sign up for a DeepDyve account if you don’t already have one.
Copy and paste the desired citation format or use the link below to download a file formatted for EndNote
Access the full text.
Sign up today, get DeepDyve free for 14 days.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.