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Ionic conduction in plasticized PVC/PAN blend polymer electrolytes

Ionic conduction in plasticized PVC/PAN blend polymer electrolytes Blended polymer electrolytes with poly(vinyl chloride) (PVC)–poly(acrylonitrile) (PAN) were prepared with different plasticizer concentrations and constant lithium perchlorate (LiClO4) ratio by the solution-casting technique. The structure and complexation of the prepared films were studied by X-ray diffraction and Fourier transform infrared spectroscopy. The effect of the plasticizer on the ionic conduction in these electrolytes was investigated using alternating current impedance measurement and discussed. The temperature-dependant ionic conductivity was carried out in the range 302–373 K. The prepared films were also examined by thermogravimetry/differential thermal analysis to determine their thermal stability. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Ionics Springer Journals

Ionic conduction in plasticized PVC/PAN blend polymer electrolytes

Ionics , Volume 14 (2) – Sep 26, 2007

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References (27)

Publisher
Springer Journals
Copyright
Copyright © 2007 by Springer-Verlag
Subject
Chemistry; Electrochemistry; Renewable and Green Energy; Optical and Electronic Materials; Condensed Matter Physics; Energy Storage
ISSN
0947-7047
eISSN
1862-0760
DOI
10.1007/s11581-007-0160-5
Publisher site
See Article on Publisher Site

Abstract

Blended polymer electrolytes with poly(vinyl chloride) (PVC)–poly(acrylonitrile) (PAN) were prepared with different plasticizer concentrations and constant lithium perchlorate (LiClO4) ratio by the solution-casting technique. The structure and complexation of the prepared films were studied by X-ray diffraction and Fourier transform infrared spectroscopy. The effect of the plasticizer on the ionic conduction in these electrolytes was investigated using alternating current impedance measurement and discussed. The temperature-dependant ionic conductivity was carried out in the range 302–373 K. The prepared films were also examined by thermogravimetry/differential thermal analysis to determine their thermal stability.

Journal

IonicsSpringer Journals

Published: Sep 26, 2007

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