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- Publisher
- Springer Journals
- Copyright
- Copyright © 2010 by Springer-Verlag
- Subject
- Chemistry; Condensed Matter Physics; Optical and Electronic Materials; Renewable and Green Energy; Electrochemistry
- ISSN
- 0947-7047
- eISSN
- 1862-0760
- DOI
- 10.1007/s11581-010-0479-1
- Publisher site
- See Article on Publisher Site
Abstract
The electronic structure of a solid electrolyte/solid electrode interface (SESEI) of an all-solid-state thin film battery was investigated. The thin film battery consisted of a LiPON solid electrolyte and a LiCoO2 cathode. The lithium phosphorus oxynitride (LiPON) electrolyte was RF sputtered in a step-by-step procedure onto the cathode and investigated by photoelectron X-ray-induced spectroscopy after each deposition step. An intermediate layer was found—composed of some new species—that differs in its chemical composition from the cathode as well as the LiPON solid electrolyte material and changes with growing layer thickness. In contrast, the electronic structure of the underlying cathode material remained predominantly unchanged.
Journal
Ionics – Springer Journals
Published: Oct 12, 2010