Access the full text.
Sign up today, get DeepDyve free for 14 days.
Loading next page...
/lp/springer-journals/influence-of-carbon-additive-on-the-properties-of-spherical-li4ti5o12-EYRcONyVju
References (19)
-
Ling Wu, Xinhai Li, Zhixing Wang, Lingjun Li, Jun‐chao Zheng, Huajun Guo, Hu Qiyang, J. Fang (2009)
Synthesis and electrochemical properties of metals-doped LiFePO4 prepared from the FeSO4·7H2O waste slagJournal of Power Sources, 189
-
M. Raja, S. Mahanty, M. Kundu, R. Basu (2009)
Synthesis of nanocrystalline Li4Ti5O12 by a novel aqueous combustion techniqueJournal of Alloys and Compounds, 468
-
Jian Gao, Changyin Jiang, J. Ying, C. Wan (2006)
Preparation and characterization of high-density spherical Li4Ti5O12 anode material for lithium secondary batteriesJournal of Power Sources, 155
-
G. Wang, Jie Gao, L. Fu, N. Zhao, Yuping Wu, T. Takamura (2007)
Preparation and characteristic of carbon-coated Li4Ti5O12 anode materialJournal of Power Sources, 174
-
John Christensen, V. Srinivasan, J. Newman (2006)
Optimization of Lithium Titanate Electrodes for High-Power CellsJournal of The Electrochemical Society, 153
-
Shahua Huang, Z. Wen, Zhonghua Gu, Xiujian Zhu (2005)
Preparation and cycling performance of Al3+ and F- co-substituted compounds Li4AlxTi5-xFyO12-yElectrochimica Acta, 50
-
Hao Liu, Peng Zhang, Guichao Li, Q. Wu, Yuping Wu (2008)
LiFePO4/C composites from carbothermal reduction methodJournal of Solid State Electrochemistry, 12
-
Hao Liu, Q. Cao, L. Fu, C. Li, Yuping Wu, H. Wu (2006)
Doping effects of zinc on LiFePO4 cathode material for lithium ion batteriesElectrochemistry Communications, 8
-
Chunhai Jiang, M. Ichihara, I. Honma, Haoshen Zhou (2007)
Effect of particle dispersion on high rate performance of nano-sized Li4Ti5O12 anodeElectrochimica Acta, 52
-
A. Shenouda, K. Murali (2008)
Electrochemical properties of doped lithium titanate compounds and their performance in lithium rechargeable batteriesJournal of Power Sources, 176
-
H. Liu, C. Li, Q. Cao, Y. Wu, R. Holze (2008)
Effects of heteroatoms on doped LiFePO4/C compositesJournal of Solid State Electrochemistry, 12
-
R. Dominko, M. Bele, M. Gaberšček, M. Remškar, D. Hanzel, S. Pejovnik, J. Jamnik (2005)
Impact of the Carbon Coating Thickness on the Electrochemical Performance of LiFePO4 / C CompositesJournal of The Electrochemical Society, 152
-
A. Guerfi, S. Sevigny, M. Lagacé, P. Hovington, K. Kinoshita, K. Zaghib (2003)
Nano-particle Li4Ti5O12 spinel as electrode for electrochemical generatorsJournal of Power Sources, 119
-
T. Ohzuku, A. Ueda, N. Yamamoto (1995)
Zero‐Strain Insertion Material of Li [ Li1 / 3Ti5 / 3 ] O 4 for Rechargeable Lithium CellsJournal of The Electrochemical Society, 142
-
Jian Gao, J. Ying, Changyin Jiang, C. Wan (2007)
High-density spherical Li4Ti5O12/C anode material with good rate capability for lithium ion batteriesJournal of Power Sources, 166
-
A. Padhi, K. Nanjundaswamy, J. Goodenough (1997)
Phospho‐olivines as Positive‐Electrode Materials for Rechargeable Lithium BatteriesJournal of The Electrochemical Society, 144
-
Jian Gao, J. Ying, Changyin Jiang, C. Wan (2009)
Preparation and characterization of spherical La-doped Li4Ti5O12 anode material for lithium ion batteriesIonics, 15
-
Yong‐Sheng Hu, Yu‐Guo Guo, R. Dominko, M. Gaberšček, J. Jamnik, J. Maier (2007)
Improved Electrode Performance of Porous LiFePO4 Using RuO2 as an Oxidic Nanoscale InterconnectAdvanced Materials, 19
-
J. Ying, Min Lei, Changyin Jiang, C. Wan, Xiangming He, Jianjun Li, Li Wang, J. Ren (2006)
Preparation and characterization of high-density spherical Li0.97Cr0.01FePO4/C cathode material for lithium ion batteriesJournal of Power Sources, 158
- Publisher
- Springer Journals
- Copyright
- Copyright © 2010 by Springer-Verlag
- Subject
- Chemistry; Condensed Matter Physics; Optical and Electronic Materials; Renewable and Green Energy; Electrochemistry
- ISSN
- 0947-7047
- eISSN
- 1862-0760
- DOI
- 10.1007/s11581-010-0423-4
- Publisher site
- See Article on Publisher Site
Abstract
Preparing spherical particles with carbon additive is considered as one effective way to improve both high rate performance and tap density of Li4Ti5O12 and LiFePO4 materials. Spherical Li4Ti5O12/C and LiFePO4/C composites are prepared by spray-drying–solid-state reaction method and controlled crystallization–carbothermal reduction method, respectively. The X-ray diffraction characterization, scanning electron microscope, Brunauer–Emmett–Teller, alternating current impedance analyzing, tap density testing, and electrochemical property measurements are investigated. After hybridizing carbon with a proper quantity, the crystal grain size of active materials is remarkably decreased and the electrochemical properties are obviously improved. The Li4Ti5O12/C and LiFePO4/C composites prepared in this work are spherical. The tap density and the specific surface area are as high as 1.71 g cm−3 and 8.26 m2 g−1 for spherical Li4Ti5O12/C, which are 1.35 g cm−3 and 18.86 m2 g−1 for spherical LiFePO4/C powders. Between 1.0 and 3.0 V versus Li, the reversible specific capacity of the Li4Ti5O12/C is more than 150 mAh g−1 at 1.0-C rate. Between 2.5 and 4.2 V versus Li, the reversible capacity of the LiFePO4/C is close to 140 mAh g−1 at 1.0-C rate.
Journal
Ionics – Springer Journals
Published: Feb 23, 2010