Access the full text.
Sign up today, get DeepDyve free for 14 days.
Wang-jun Cui, Fei Wang, Jie Wang, Hai-jing Liu, Congxiao Wang, Yongyao Xia (2011)
A modified carbothermal reduction method for preparation of high-performance nano-scale core/shell CThe Lancet
Haibin Lin, Y. Zhang, J. Hu, Yuanzhou Wang, L. Xing, Mengqing Xu, X. Li, W. Li (2014)
LiNi0.5Mn1.5O4 nanoparticles: Synthesis with synergistic effect of polyvinylpyrrolidone and ethylene glycol and performance as cathode of lithium ion batteryJournal of Power Sources, 257
S. Prabakar, S. Han, S. Singh, Dong Lee, K. Sohn, M. Pyo (2012)
W-doped LiWxNi0.5Mn1.5−xO4 cathodes for the improvement of high rate performances in Li ion batteriesJournal of Power Sources, 209
Haibin Lin, Y. Zhang, H. Rong, S. Mai, J. Hu, Youhao Liao, L. Xing, Mengqing Xu, Xiaoping Li, Weishan Li (2014)
Crystallographic facet- and size-controllable synthesis of spinel LiNi0.5Mn1.5O4 with excellent cyclic stability as cathode of high voltage lithium ion batteryJournal of Materials Chemistry, 2
C. Julien, A. Mauger (2013)
Review of 5-V electrodes for Li-ion batteries: status and trendsIonics, 19
L. Xing, Weishan Li, Chaoyang Wang, Fenglong Gu, Mengqing Xu, C. Tan, Jin Yi (2009)
Theoretical investigations on oxidative stability of solvents and oxidative decomposition mechanism of ethylene carbonate for lithium ion battery use.The journal of physical chemistry. B, 113 52
Y. Talyosef, B. Markovsky, G. Salitra, D. Aurbach, Hyeong-Jin Kim, Seung-Don Choi (2005)
The study of LiNi0.5Mn1.5O4 5-V cathodes for Li-ion batteriesJournal of Power Sources, 146
G. Appetecchi, F. Croce, G. Dautzenberg, M. Mastragostino, F. Ronci, B. Scrosati, F. Soavi, A. Zanelli, F. Alessandrini, P. Prosini (1998)
Composite polymer electrolytes with improved lithium metal electrode interfacial properties: I. Electrochemical properties of dry PEO-LiX systemsJournal of The Electrochemical Society, 145
Youhao Liao, D. Zhou, M. Rao, Weishan Li, Zongping Cai, Ying Liang, C. Tan (2009)
Self-supported poly(methyl methacrylate–acrylonitrile–vinyl acetate)-based gel electrolyte for lithium ion batteryJournal of Power Sources, 189
Yun‐Sung Lee, Yang‐Kook Sun, S. Ota, T. Miyashita, M. Yoshio (2002)
Preparation and characterization of nano-crystalline LiNi0.5Mn1.5O4 for 5 V cathode material by composite carbonate processElectrochemistry Communications, 4
L. Xing, Weishan Li, Mengqing Xu, Tiantian Li, Zhou Liu (2011)
The reductive mechanism of ethylene sulfite as solid electrolyte interphase film-forming additive foThe Lancet
Dongrui Chen, Benzhen Li, Youhao Liao, H. Lan, Haibin Lin, L. Xing, Yating Wang, Weishan Li (2014)
Improved electrochemical performance of LiNi0.5Mn1.5O4 as cathode of lithium ion battery by Co and Cr co-dopingJournal of Solid State Electrochemistry, 18
Hao Li, Chen Yue-ming, Xiaoting Ma, Junli Shi, Bao-ku Zhu, Li-ping Zhu (2011)
Gel polymer electrolytes based on active PVDF separator for lithium ion battery. I: Preparation andFuel and Energy Abstracts
Young‐Kyu Han, Jaehoon Jung, Sunghun Yu, Hochun Lee (2009)
Understanding the characteristics of high-voltage additives in Li-ion batteries : Solvent effectsJournal of Power Sources, 187
P. Sun, Youhao Liao, Huilin Xie, Tingting Chen, M. Rao, Weishan Li (2014)
Poly(methyl methacrylate-acrylonitrile-ethyl acrylate) terpolymer based gel electrolyte for LiNi 0.5 Mn 1.5 O 4 cathode of high voltage lithium ion batteryJournal of Power Sources, 269
C. M.S., S. Mitra (2013)
Electrodeposition of iron phosphide on copper substrate as conversion negative electrode for lithium-ion battery applicationIonics, 20
M. Rao, Xiuyu Geng, Youhao Liao, She-jun Hu, Weishan Li (2012)
Preparation and performance of gel polymer electrolyte based on electrospun polymer membrane and ionic liquid for lithium ion batteryJournal of Membrane Science, 399
G. Armstrong, A. Armstrong, P. Bruce, P. Reale, B. Scrosati (2006)
TiO2(B) Nanowires as an Improved Anode Material for Lithium‐Ion Batteries Containing LiFePO4 or LiNi0.5Mn1.5O4 Cathodes and a Polymer ElectrolyteAdvanced Materials, 18
Liang Xue, Youhao Liao, Liang Yang, Xiaoping Li, Weishan Li (2015)
Improved rate performance of LiNi0.5Mn1.5O4 cathode for lithium ion battery by carbon coatingIonics, 21
S. Dalavi, Mengqing Xu, B. Ravdel, Liu Zhou, B. Lucht (2010)
Nonflammable Electrolytes for Lithium-Ion Batteries Containing Dimethyl MethylphosphonateJournal of The Electrochemical Society, 157
J. Arrebola, Á. Caballero, M. Cruz, L. Hernán, J. Morales, E. Castellón (2006)
Crystallinity Control of a Nanostructured LiNi0.5Mn1.5O4 Spinel via Polymer‐Assisted Synthesis: A Method for Improving Its Rate Capability and Performance in 5 V Lithium BatteriesAdvanced Functional Materials, 16
Huilin Xie, Youhao Liao, P. Sun, Tingting Chen, M. Rao, Weishan Li (2014)
Investigation on polyethylene-supported and nano-SiO2 doped poly(methyl methacrylate-co-butyl acrylate) based gel polymer electrolyte for high voltage lithium ion batteryElectrochimica Acta, 127
D. Lu, Weishan Li, Xiaoxi Zuo, andXin Yuan, Qiming Huang (2007)
Study on electrode kinetics of Li+ insertion in LixMn2O4 (0 < x < 1) by electrochemical impedance spectroscopyJournal of Physical Chemistry C, 111
Yunjian Liu, Long Chen (2012)
Study on the electrochemical performance of LiNi0.5Mn1.5O4 with different precursorIonics, 18
D. Aurbach, E. Zinigrad, Y. Cohen, Hanan Teller (2002)
A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutionsSolid State Ionics, 148
Meng Hu, X. Pang, Zhen Zhou (2013)
Recent progress in high-voltage lithium ion batteriesJournal of Power Sources, 237
Jiangang Li, Yayuan Zhang, Jianjun Li, Li Wang, Xiangming He, Jian Gao (2011)
AlF3 coating of LiNi0.5Mn1.5O4 for high-performance Li-ion batteriesIonics, 17
Tingfeng Yi, Ying Xie, Mingfu Ye, Li-juan Jiang, Rongsun Zhu, Yan-Rong Zhu (2011)
Recent developments in the doping of LiNi0.5Mn1.5O4 cathode material for 5 V lithium-ion batteriesIonics, 17
M. Aklalouch, J. Amarilla, R. Rojas, I. Saadoune, J. Rojo (2010)
Sub-micrometric LiCr0.2Ni0.4Mn1.4O4 spinel as 5 V-cathode material exhibiting huge rate capability at 25 and 55 CElectrochemistry Communications, 12
J. Hassoun, S. Panero, P. Reale, B. Scrosati (2009)
A New, Safe, High‐Rate and High‐Energy Polymer Lithium‐Ion BatteryAdvanced Materials, 21
Zixiu Li, H. Zhang, Peng Zhang, Guichao Li, Yuping Wu, X. Zhou (2008)
Effects of the porous structure on conductivity of nanocomposite polymer electrolyte for lithium ion batteriesJournal of Membrane Science, 322
T. Yang, Naiqing Zhang, Ye Lang, Kening Sun (2011)
Enhanced rate performance of carbon-coated LiNi0.5Mn1.5O4 cathode material for lithium ion batteriesElectrochimica Acta, 56
Y. Liao, Xin Li, C. Fu, R. Xu, M. Rao, Liu Zhou, Shi Hu, W. Li (2011)
Performance improvement of polyethylene-supported poly(methyl methacrylate-vinyl acetate)- co-poly(eThe Lancet
Youhao Liao, M. Rao, Weishan Li, C. Tan, Jin Yi, Lang Chen (2009)
Improvement in ionic conductivity of self-supported P(MMA-AN-VAc) gel electrolyte by fumed silica for lithium ion batteriesElectrochimica Acta, 54
Tingfeng Yi, Ying Xie, Yan-Rong Zhu, Rongsun Zhu, Mingfu Ye (2012)
High rate micron-sized niobium-doped LiMn1.5Ni0.5O4 as ultra high power positive-electrode material for lithium-ion batteriesJournal of Power Sources, 211
Y. Watanabe, S. Kinoshita, S. Wada, Keiji Hoshino, H. Morimoto, S. Tobishima (2008)
Electrochemical properties and lithium ion solvation behavior of sulfone–ester mixed electrolytes for high-voltage rechargeable lithium cellsJournal of Power Sources, 179
A. Gopalan, P. Santhosh, K. Manesh, Jin Nho, Sang-Ho Kim, C. Hwang, Kwang-Pil Lee (2008)
Development of electrospun PVdF-PAN membrane-based polymer electrolytes for lithium batteriesJournal of Membrane Science, 325
Youhao Liao, M. Rao, Weishan Li, L. Yang, Bao-ku Zhu, R. Xu, C. Fu (2010)
Fumed silica-doped poly(butyl methacrylate-styrene)-based gel polymer electrolyte for lithium ion batteryJournal of Membrane Science, 352
Youhao Liao, X. Li, C. Fu, R. Xu, Liu Zhou, C. Tan, She-jun Hu, Weishan Li (2011)
Polypropylene-supported and nano-Al2O3 doped poly(ethylene oxide)–poly(vinylidene fluoride-hexafluoropropylene)-based gel electrolyte for lithium ion batteriesJournal of Power Sources, 196
Liang Xue, Xiaoping Li, Youhao Liao, L. Xing, Mengqing Xu, Weishan Li (2015)
Effect of particle size on rate capability and cyclic stability of LiNi0.5Mn1.5O4 cathode for high-voltage lithium ion batteryJournal of Solid State Electrochemistry, 19
Li Yang, B. Ravdel, B. Lucht (2010)
Electrolyte Reactions with the Surface of High Voltage LiNi0.5Mn1.5O4 Cathodes for Lithium-Ion BatteriesElectrochemical and Solid State Letters, 13
D. Djian, F. Alloin, S. Martinet, H. Lignier (2009)
Macroporous poly(vinylidene fluoride) membrane as a separator for lithium-ion batteries with high charge rate capacityJournal of Power Sources, 187
Jin Yi, Congxiao Wang, Yongyao Xia (2013)
Comparison of thermal stability between micro- and nano-sized materials for lithium-ion batteriesElectrochemistry Communications, 33
Youhao Liao, C. Sun, She-jun Hu, Weishan Li (2013)
Anti-thermal shrinkage nanoparticles/polymer and ionic liquid based gel polymer electrolyte for lithium ion batteryElectrochimica Acta, 89
J. Arrebola, Á. Caballero, L. Hernán, J. Morales (2010)
Re-examining the effect of ZnO on nanosized 5 V LiNi0.5Mn1.5O4 spinel: An effective procedure for enhancing its rate capability at room and high temperaturesJournal of Power Sources, 195
Felix Dias, L. Plomp, J. Veldhuis (2000)
Trends in polymer electrolytes for secondary lithium batteriesJournal of Power Sources, 88
Zixiu Li, Peng Zhang, H. Zhang, Yuping Wu, X. Zhou (2008)
A lotus root-like porous nanocomposite polymer electrolyteElectrochemistry Communications, 10
Huiming Wu, I. Belharouak, A. Abouimrane, Yang‐Kook Sun, K. Amine (2010)
Surface modification of LiNi0.5Mn1.5O4 by ZrP2O7 and ZrO2 for lithium-ion batteriesJournal of Power Sources, 195
Benzhen Li, L. Xing, Mengqing Xu, Haibin Lin, Weishan Li (2013)
New solution to instability of spinel LiNi0.5Mn1.5O4 as cathode for lithium ion battery at elevated temperatureElectrochemistry Communications, 34
Yi-Chun Jin, C. Lin, J. Duh (2012)
Improving rate capability of high potential LiNi0.5Mn1.5O4−x cathode materials via increasing oxygen non-stoichiometriesElectrochimica Acta, 69
P. Kumar, M. Venkateswarlu, M. Misra, A. Mohanty, N. Satyanarayana (2013)
Enhanced conductivity and electrical relaxation studies of carbon-coated LiMnPO4 nanorodsIonics, 19
LiNi0.5Mn1.5O4 is synthesized by a sol–gel method, and its performance as cathode of high-voltage lithium-ion battery is improved by using poly(vinylidene fluoride-co-hexafluoropropene)-based gel polymer electrolyte (GPE). The results obtained from charge/discharge tests demonstrate that the cyclic stability of LiNi0.5Mn1.5O4 is significantly improved by using the GPE, especially at elevated temperature. After 150 cycles, the discharge capacity of LiNi0.5Mn1.5O4 drops sharply from 127 to 60 mAh g−1 when using liquid electrolyte, while remaining a high value when using GPE, from 134 to 124 mAh g−1. The improved performance is attributed to the enhanced stability of the electrolyte when substituting GPE for liquid electrolyte.
Ionics – Springer Journals
Published: Apr 12, 2015
Read and print from thousands of top scholarly journals.
Already have an account? Log in
Bookmark this article. You can see your Bookmarks on your DeepDyve Library.
To save an article, log in first, or sign up for a DeepDyve account if you don’t already have one.
Copy and paste the desired citation format or use the link below to download a file formatted for EndNote
Access the full text.
Sign up today, get DeepDyve free for 14 days.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.