Access the full text.
Sign up today, get DeepDyve free for 14 days.
Jinhu Li, C. Lee, H. Park, Y. Lee (2006)
Novel sulfonated poly(arylene ether ketone) containing benzoxazole membranes for proton exchange membrane fuel cellMacromolecular Research, 14
J. Won, H. Park, Young Kim, Sang-Goo Choi, H. Ha, I. Oh, H. Kim, Y. Kang, K. Ihn (2003)
Fixation of nanosized proton transport channels in membranesMacromolecules, 36
N. Carretta, V. Tricoli, F. Picchioni (2000)
Ionomeric membranes based on partially sulfonated poly(styrene): synthesis, proton conduction and methanol permeationJournal of Membrane Science, 166
M. Muthukumar, J. Ho (1989)
Self-consistent field theory of surfaces with terminally attached chainsMacromolecules, 22
Y. Elabd, C. Walker, F. Beyer (2004)
Triblock copolymer ionomer membranes Part II. Structure characterization and its effects on transport properties and direct methanol fuel cell performanceJournal of Membrane Science, 231
J. S. Kim (1998)
Introduction to Ionomers
K. Mauritz, R. Moore (2004)
State of understanding of nafion.Chemical reviews, 104 10
Hae-Seung Lee, A. Roy, A. Badami, J. Mcgrath (2007)
Synthesis and characterization of sulfonated poly(arylene ether) polyimide multiblock copolymers for proton exchange membranesMacromolecular Research, 15
Tae-kyoung Kim, Myeongsoon Kang, Y. Choi, H. Kim, W. Lee, Hyuk Chang, D. Seung (2007)
Preparation of Nafion-sulfonated clay nanocomposite membrane for direct menthol fuel cells via a film coating processJournal of Power Sources, 165
G. Moon, J. Rhim (2008)
Self-assembly modification of perfluorosulfonic acid membranes for the application to direct methanol fuel cellsMacromolecular Research, 16
Wonmok Lee, H. Kim, Hyunjung Lee (2008)
Proton exchange membrane using partially sulfonated polystyrene-b-poly(dimethylsiloxane) for direct methanol fuel cellJournal of Membrane Science, 320
K. Winey, E. Thomas, L. Fetters (1991)
Swelling of lamellar diblock copolymer by homopolymer: influences of homopolymer concentration and molecular weightMacromolecules, 24
M. Hickner, H. Ghassemi, Y. Kim, B. Einsla, J. Mcgrath (2004)
Alternative polymer systems for proton exchange membranes (PEMs).Chemical reviews, 104 10
R. Weiss, A. Sen, C. Willis, L. Pottick (1991)
Block copolymer ionomers: 1. Synthesis and physical properties of sulphonated poly(styrene-ethylene/butylene-styrene)Polymer, 32
B. Efron, R. Tibshirani (1994)
An Introduction to the Bootstrap
Conclusions To improve the mechanical property of sPS-b-PDMS proton conducting membrane for DMFC application, crosslinkable PDMS oligomer has been incorporated within the BCP ionomer. Premixing different amount of Sylgard 184 PDMS in the ionomer solution, and subsequent membrane casting and thermal curing revealed that the composite membrane containing 5 wt% of Sylgard 184 showed enhanced properties in the uniaxial tensile strength, toughness, methanol permeability, and even in the proton conductance. This results show that the PDMS oligomers were successfully sequestered within PDMS block of sPS-b-PDMS during casting procedure, and safely crosslinked without deterioration of the membrane microphase structure.
"Macromolecular Research" – Springer Journals
Published: Jun 1, 2009
Read and print from thousands of top scholarly journals.
Already have an account? Log in
Bookmark this article. You can see your Bookmarks on your DeepDyve Library.
To save an article, log in first, or sign up for a DeepDyve account if you don’t already have one.
Copy and paste the desired citation format or use the link below to download a file formatted for EndNote
Access the full text.
Sign up today, get DeepDyve free for 14 days.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.