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Hydrothermal Synthesis and Physicochemical Characterization of Organic-Inorganic Isopolyoxomolybdate-Based Hybrid (C6N6)4[H4Mo8O26]

Hydrothermal Synthesis and Physicochemical Characterization of Organic-Inorganic... A novel polyoxomolybdate-based organic-inorganic hybrid compound, (C6H6)4[H4Mo8O26], has been synthesized hydrothermally and characterized structurally by the elemental analysis, single crystal X-ray diffraction, thermogravimetric analysis, infrared and ultraviolet–visible spectroscopies, and cyclic voltammetry. Crystallographic data for the compound are: triclinic system, space group \documentclass[12pt]{minimal}\usepackage{amsmath}\usepackage{wasysym}\usepackage{amsfonts}\usepackage{amssymb}\usepackage{amsbsy}\usepackage{mathrsfs}\usepackage{upgreek}\setlength{\oddsidemargin}{-69pt}\begin{document}$$P\mathop 1\limits^\_ $$\end{document}, unit cell parameters a = 9.605(2)  Å, b = 9.991(3) Å, c = 10.718(3) Å, α = 83.75(2)°, β = 76.45(3)°, γ = 69.07(3)°, Z = 1. The crystal consists of the clusters β-[Mo8O26]4– and four organic molecules C6H6. Isopolymolybdate anions are connected with the organic molecules via a complex hydrogen-bonded network, which generate a three-dimensional framework. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Crystallography Reports Springer Journals

Hydrothermal Synthesis and Physicochemical Characterization of Organic-Inorganic Isopolyoxomolybdate-Based Hybrid (C6N6)4[H4Mo8O26]

Crystallography Reports , Volume 64 (7) – Dec 25, 2019

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References (37)

Publisher
Springer Journals
Copyright
Copyright © Pleiades Publishing, Inc. 2019
ISSN
1063-7745
eISSN
1562-689X
DOI
10.1134/S1063774519070058
Publisher site
See Article on Publisher Site

Abstract

A novel polyoxomolybdate-based organic-inorganic hybrid compound, (C6H6)4[H4Mo8O26], has been synthesized hydrothermally and characterized structurally by the elemental analysis, single crystal X-ray diffraction, thermogravimetric analysis, infrared and ultraviolet–visible spectroscopies, and cyclic voltammetry. Crystallographic data for the compound are: triclinic system, space group \documentclass[12pt]{minimal}\usepackage{amsmath}\usepackage{wasysym}\usepackage{amsfonts}\usepackage{amssymb}\usepackage{amsbsy}\usepackage{mathrsfs}\usepackage{upgreek}\setlength{\oddsidemargin}{-69pt}\begin{document}$$P\mathop 1\limits^\_ $$\end{document}, unit cell parameters a = 9.605(2)  Å, b = 9.991(3) Å, c = 10.718(3) Å, α = 83.75(2)°, β = 76.45(3)°, γ = 69.07(3)°, Z = 1. The crystal consists of the clusters β-[Mo8O26]4– and four organic molecules C6H6. Isopolymolybdate anions are connected with the organic molecules via a complex hydrogen-bonded network, which generate a three-dimensional framework.

Journal

Crystallography ReportsSpringer Journals

Published: Dec 25, 2019

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