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Heptacoordinated Carbon and Nitrogen in a Planar Boron Ring

Heptacoordinated Carbon and Nitrogen in a Planar Boron Ring Doklady Chemistry, Vol. 382, Nos. 4–6, 2002, pp. 41–45. Translated from Doklady Akademii Nauk, Vol. 382, No. 6, 2002, pp. 785–789. Original Russian Text Copyright © 2002 by Minyaev, Gribanova, Starikov, Minkin. CHEMISTRY R. M. Minyaev, T. N. Gribanova, A. G. Starikov, and Academician V. I. Minkin Received November 8, 2001 Quantum-chemical calculations of structures with functional theory) methods (B3LYP/6-311G(2df), nontrivial geometry formed by hypercoordinated main- B3LYP/6-311+G(2df)) [13]. group elements not only contribute to the development B B B B B B of structural theory but also serve as a valuable tool for Li revealing compounds with unusual physicochemical B B B B B B X C C properties and new structural motifs that are of interest BB BB BB in materials science and molecular electronics [1, 2]. Relevant works began with theoretical studies of the B C B conditions for stabilization of a planar tetracoordinated 7 (X = C , N), D 8, C 9, C 2v 7v 7h carbon center in organic and organometallic com- As follows from DFT calculations, anion 7, D 7h pounds [3–7]. Similar conditions for stabilization of (X = C ) corresponds to an energy minimum at the PES tetracoordinated nitrogen and oxygen http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Doklady Chemistry Springer Journals

Heptacoordinated Carbon and Nitrogen in a Planar Boron Ring

Doklady Chemistry , Volume 382 (6) – Oct 10, 2004

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References (8)

Publisher
Springer Journals
Copyright
Copyright © 2002 by MAIK “Nauka/Interperiodica”
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
0012-5008
eISSN
1608-3113
DOI
10.1023/A:1014429323457
Publisher site
See Article on Publisher Site

Abstract

Doklady Chemistry, Vol. 382, Nos. 4–6, 2002, pp. 41–45. Translated from Doklady Akademii Nauk, Vol. 382, No. 6, 2002, pp. 785–789. Original Russian Text Copyright © 2002 by Minyaev, Gribanova, Starikov, Minkin. CHEMISTRY R. M. Minyaev, T. N. Gribanova, A. G. Starikov, and Academician V. I. Minkin Received November 8, 2001 Quantum-chemical calculations of structures with functional theory) methods (B3LYP/6-311G(2df), nontrivial geometry formed by hypercoordinated main- B3LYP/6-311+G(2df)) [13]. group elements not only contribute to the development B B B B B B of structural theory but also serve as a valuable tool for Li revealing compounds with unusual physicochemical B B B B B B X C C properties and new structural motifs that are of interest BB BB BB in materials science and molecular electronics [1, 2]. Relevant works began with theoretical studies of the B C B conditions for stabilization of a planar tetracoordinated 7 (X = C , N), D 8, C 9, C 2v 7v 7h carbon center in organic and organometallic com- As follows from DFT calculations, anion 7, D 7h pounds [3–7]. Similar conditions for stabilization of (X = C ) corresponds to an energy minimum at the PES tetracoordinated nitrogen and oxygen

Journal

Doklady ChemistrySpringer Journals

Published: Oct 10, 2004

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