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Growth and crystal structure of binary molybdate CsFe(MoO 4 ) 2

Growth and crystal structure of binary molybdate CsFe(MoO 4 ) 2 Abstract CsFe(MoO4)2 single crystals have been grown by solution-melt crystallization with a charge-to-solvent ratio of 1: 3 (with Cs2Mo3O10 used as a solvent). The crystal structure of this compound has been refined by X-ray diffraction (X8 APEX automatic diffractometer, MoK α radiation, 356 F(hkl), R = 0.0178). The trigonal unit cell has the following parameters: a = b = 5.6051(2) Å, c = 8.0118(4) Å, V = 217.985(15) Å3, Z = 1, ρcalc = 3.875 g/cm3, and sp. gr. P \( \bar 3 \) m1. The structure is composed of alternating layers of FeO6 octahedra (with MoO4 tetrahedra attached by sharing vertices) and CsO12 icosahedra. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Crystallography Reports Springer Journals

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References (4)

Publisher
Springer Journals
Copyright
2010 Pleiades Publishing, Ltd.
ISSN
1063-7745
eISSN
1562-689X
DOI
10.1134/S1063774510040097
Publisher site
See Article on Publisher Site

Abstract

Abstract CsFe(MoO4)2 single crystals have been grown by solution-melt crystallization with a charge-to-solvent ratio of 1: 3 (with Cs2Mo3O10 used as a solvent). The crystal structure of this compound has been refined by X-ray diffraction (X8 APEX automatic diffractometer, MoK α radiation, 356 F(hkl), R = 0.0178). The trigonal unit cell has the following parameters: a = b = 5.6051(2) Å, c = 8.0118(4) Å, V = 217.985(15) Å3, Z = 1, ρcalc = 3.875 g/cm3, and sp. gr. P \( \bar 3 \) m1. The structure is composed of alternating layers of FeO6 octahedra (with MoO4 tetrahedra attached by sharing vertices) and CsO12 icosahedra.

Journal

Crystallography ReportsSpringer Journals

Published: Jul 1, 2010

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