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Sangamithra Chintapalli, R. Frech (1996)
Effect of plasticizers on high molecular weight PEO-LiCF3SO3 complexesSolid State Ionics
Xiao-Qing Yang, Hungsui Lee, L. Hanson, J. Mcbreen, Y. Okamoto (1994)
Development of a new plasticizer for poly(ethylene oxide)-based polymer electrolyte and the investigation of their ion-pair dissociation effectJournal of Power Sources, 54
M. Furlani, L. Bandara, B. Mellander (1998)
Ionic conductivity and plasticizing effect in the system poly(ethyleneoxide)9/Li(CF3SO3)-poly(perfluoroethylmethyloxide)Electrochimica Acta, 43
D. Macfarlane, P. Meakin, Andrea Bishop, D. McNaughton, J. Rosalie, M. Forsyth (1995)
Ftir study of ion-pairing effects in plasticized polymer electrolytesElectrochimica Acta, 40
M. Reddy, T. Sreekanth, U. Rao (1999)
Study of the plasticizer effect on a (PEO+NaYF4) polymer electrolyte and its use in an electrochemical cellSolid State Ionics, 126
L. Su, Zhongdang Xiao, Zuhong Lu (1998)
All solid-state electrochromic device with PMMA gel electrolyteMaterials Chemistry and Physics, 52
M. Deepa, N. Sharma, S. Agnihotry, R. Chandra (2002)
FTIR investigations on ion–ion interactions in liquid and gel polymeric electrolytes: LiCF3SO3-PC-PMMAJournal of Materials Science, 37
T. Winie, A. Arof (2006)
FT-IR studies on interactions among components in hexanoyl chitosan-based polymer electrolytes.Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 63 3
J. Southall, H.V.St.A. Hubbard, S. Johnston, V. Rogers, G. Davies, J. Mcintyre, I. Ward (1996)
Ionic conductivity and viscosity correlations in liquid electrolytes for incorporation into PVDF gel electrolytesSolid State Ionics, 85
Hyun-Soo Kim, Jungwon Shin, S. Moon, Sang-Pil Kim (2003)
Preparation of gel polymer electrolytes using PMMA interpenetrating polymeric network and their electrochemical performancesElectrochimica Acta, 48
Z. Osman, Z. Ibrahim, A. Arof (2001)
Conductivity enhancement due to ion dissociation in plasticized chitosan based polymer electrolytesCarbohydrate Polymers, 44
R. Frech, Sangamithra Chintapalli (1996)
Effect of propylene carbonate as a plasticizer in high molecular weight PEOLiCF3SO3 electrolytesSolid State Ionics, 85
M. Jacob, A. Arof (2000)
FTIR studies of DMF plasticized polyvinyledene fluoride based polymer electrolytesElectrochimica Acta, 45
James Robinson, Eileen Frame, G. Frame (2008)
Introduction to SpectroscopyInstrumental Analytical Chemistry
Andrea Bishop, D. Macfarlane, D. McNaughton, M. Forsyth (1996)
Triflate ion association in plasticized polymer electrolytesSolid State Ionics, 85
R. Armstrong (1974)
The metal-solid electrolyte interphaseJournal of Electroanalytical Chemistry, 52
X. Andrieu, T. Vicedo, C. Fringant (1995)
Plasticization of cross-linked polymer electrolytesJournal of Power Sources, 54
F. Gray (1991)
Solid Polymer Electrolytes: Fundamentals and Technological Applications
D. Fenton, J. Parker, P. Wright (1973)
Complexes of alkali metal ions with poly(ethylene oxide)Polymer, 14
M. Deepa, S. Agnihotry, Devinder Gupta, R. Chandra (2004)
Ion-pairing effects and ion–solvent–polymer interactions in LiN(CF3SO2)2–PC–PMMA electrolytes: a FTIR studyElectrochimica Acta, 49
Wan-Jin Lee, H. Jung, M. Lee, Jong‐Ho Kim, K. Yang (2003)
Preparation and ionic conductivity of sulfonated-SEBS/SiO2/plasticizer composite polymer electrolyte for polymer batterySolid State Ionics, 164
J. Vondrak, J. Reiter, J. Velická, B. Klápště, M. Sedlaříková, Jan Dvořák (2005)
Ion-conductive polymethylmethacrylate gel electrolytes for lithium batteriesJournal of Power Sources, 146
C. Reddy, A. Sharma, V. Rao (2002)
Effect of plasticizer on electrical conductivity and cell parameters of PVP + PVA + KClO3 blend polymer electrolyte systemJournal of Power Sources, 111
V. Arjunan, S. Subramanian, S. Mohan (2001)
Fourier transform infrared and Raman spectral analysis of trans-1,4-polyisoprene.Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 57 13
R. Idris, M. Glasse, R. Latham, R. Linford, W. Schlindwein (2001)
Polymer electrolytes based on modified natural rubber for use in rechargeable lithium batteriesJournal of Power Sources, 94
P. Periasamy, K. Tatsumi, M. Shikano, T. Fujieda, T. Sakai, Y. Saito, M. Mizuhata, A. Kajinami, S. Deki (1999)
An electrochemical investigation on polyvinylidene fluoride-based gel polymer electrolytesSolid State Ionics, 126
R. Subban, A. Arof (2004)
Plasticiser interactions with polymer and salt in PVC-LiCF3SO3-DMF electrolytesEuropean Polymer Journal, 40
M. Glasse, R. Idris, R. Latham, R. Linford, W. Schlindwein (2000)
Polymer electrolytes based on modified natural rubberSolid State Ionics, 147
J. Maccallum, C. Vincent (1987)
Polymer electrolyte reviews. 1
K. Kumutha, Y. Alias (2006)
FTIR spectra of plasticized grafted natural rubber-LiCF3SO3 electrolytes.Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 64 2
M. Nasef, H. Saidi (2006)
Structural, thermal and ion transport properties of radiation grafted lithium conductive polymer electrolytesMaterials Chemistry and Physics, 99
A. Stephan, T. Kumar, N. Renganathan, S. Pitchumani, R. Thirunakaran, N. Muniyandi (2000)
Ionic conductivity and FT-IR studies on plasticized PVC/PMMA blend polymer electrolytesJournal of Power Sources, 89
Josefina Adebahr, Patrik Gavelin, P. Jannasch, D. Ostrovskii, B. Wesslén, P. Jacobsson (2000)
Cation coordination in ion-conducting gels based on PEO-grafted polymersSolid State Ionics, 135
C. Jarvis, W. Macklin, A. Macklin, N. Mattingley, E. Kronfli (2001)
Use of grafted PVdF-based polymers in lithium batteriesJournal of Power Sources, 97
N. Dafader, M. Haque, F. Akhtar, M. Ahmad (2006)
Study on grafting of different types of acrylic monomers onto natural rubber by γ-raysRadiation Physics and Chemistry, 75
B. Scrosati, A. Magistris, C. Mari, G. Mariotto (1993)
Fast Ion Transport in Solids
M. Dissanayake, M. Careem (1988)
Electrical conductivity of the Li2SO4CaSO4 and Li2SO4MgSO4 systemsSolid State Ionics
S. Rajendran, M. Sivakumar, R. Subadevi (2004)
Investigations on the effect of various plasticizers in PVA–PMMA solid polymer blend electrolytesMaterials Letters, 58
M. Yahya, A. Arof (2003)
Effect of oleic acid plasticizer on chitosan–lithium acetate solid polymer electrolytesEuropean Polymer Journal, 39
P. Ferloni, M. Mastragostino, L. Meneghello (1996)
Impedance analysis of electronically conducting polymersElectrochimica Acta, 41
D. Battisti, G. Nazri, B. Klassen, R. Aroca (1993)
Vibrational studies of lithium perchlorate in propylene carbonate solutionsThe Journal of Physical Chemistry, 97
S. Starkey, R. Frech (1997)
Plasticizer interactions with polymer and salt in propylene carbonate-poly(acrylonitrile)-lithium triflateElectrochimica Acta, 42
Attenuated total reflectance–Fourier transformed infrared spectroscopy measurement is employed to study the interactions between the components of 30% methyl-grafted natural rubber (MG30), lithium trifluromethanesulfonate (LiCF3SO3 or LiTF), and propylene carbonate (PC). Vibrational spectra data of LiTF reveals that the νs(SO3) at 1,045 cm−1, δs(CF3) at 777 cm−1, and C=O stretching mode at 1,728 cm−1 for MG30 have shifted to lower wave numbers in MG30–LiTF complexes indicating that complexation has occurred between MG30 and LiTF. The solvation of lithium ion is manifested in Li+ ← O=C interaction as shown by the downshifting and upshifting of C=O mode at 1,788 to 1,775 cm−1 and νas(SO3) at 1,250 to 1258 cm−1, respectively, in LiTF–PC electrolytes. There is no experimental evidence of the interaction between MG30 and PC. Competition between MG30 and PC on associating with lithium ion is studied, and the studies show that the interaction between MG30–LiTF is stronger than that of the PC–LiTF in plasticized polymer–salt complexes. The effect of PC on the ionic conductivity of the MG30–LiTF system is explained in terms of the polymer, plasticizer, and salt interactions. The temperature dependence of conductivity of the polymer films obeys the Vogel–Tamman–Fulcher relation. Values of conductivity and activation energy of the MG30-based polymer electrolyte systems are presented and discussed.
Ionics – Springer Journals
Published: Jan 14, 2008
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