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It was experimentally determined for the first time that, for noncatalytic biodiesel synthesis, the dependence of the partial pressure of methanol on the mole fraction of methanol in rapeseed oil shows a pronounced negative deviation from Raoult’s law. Investigation of the change in the partial pressure of methanol in the noncatalytic reaction of the transesterification of rapeseed oil in 8 h of the reaction at 220°C demonstrated that the efficiency of the increase in the molar excess of methanol decreases, and, at a more than 10-fold molar excess, the amount of the reacted methanol remains unchanged.
Doklady Chemistry – Springer Journals
Published: Jul 16, 2020
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