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Electrons of l shells of free atoms as a regular system of points on a sphere: II. Some manifestations of the symmetry of electron shells of ions of transition metals in ordered media

Electrons of l shells of free atoms as a regular system of points on a sphere: II. Some... Abstract Manifestations of the spatial symmetry of d and f shells formed by equivalent electrons of transition-metal ions in crystals and other ordered media are considered. It is shown that sizes of crystals and the rare coordination number of ions can be explained in terms of the noncrystallographic symmetry of these shells. The symmetry of the d shell may cause manifestations of elements of fivefold symmetry in the crystal faceting and the structure of molecules and affect the properties dependent on matching of the intrinsic symmetry of the shell and the translational symmetry of a crystal. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Crystallography Reports Springer Journals

Electrons of l shells of free atoms as a regular system of points on a sphere: II. Some manifestations of the symmetry of electron shells of ions of transition metals in ordered media

Veremeĭchik, T. F.; Galiulin, R. V.
Crystallography Reports , Volume 49 (6): 8 – Nov 1, 2004
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References (27)

Publisher
Springer Journals
Copyright
2004 MAIK "Nauka/Interperiodica"
ISSN
1063-7745
eISSN
1562-689X
DOI
10.1134/1.1828131
Publisher site
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Abstract

Abstract Manifestations of the spatial symmetry of d and f shells formed by equivalent electrons of transition-metal ions in crystals and other ordered media are considered. It is shown that sizes of crystals and the rare coordination number of ions can be explained in terms of the noncrystallographic symmetry of these shells. The symmetry of the d shell may cause manifestations of elements of fivefold symmetry in the crystal faceting and the structure of molecules and affect the properties dependent on matching of the intrinsic symmetry of the shell and the translational symmetry of a crystal.

Journal

Crystallography Reports – Springer Journals

Published: Nov 1, 2004

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