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ISSN 00125008, Doklady Chemistry, 2009, Vol. 428, Part 1, pp. 218–221. © Pleiades Publishing, Ltd., 2009. Original Russian Text © S.A. Kuznetsov, V.V. Grinevich, A.V. Arakcheeva, V.T. Kalinnikov, 2009, published in Doklady Akademii Nauk, 2009, Vol. 428, No. 2, pp. 199–202. CHEMISTRY Electrochemical Synthesis of Tantalum Monoxide Nanoneedles in Molten Salts a b b a S. A. Kuznetsov , V. V. Grinevich , A. V. Arakcheeva , and Academician V. T. Kalinnikov Received March 10, 2009 DOI: 10.1134/S0012500809090043 In spite of numerous studies on the chemistry of us to avoid contact of oxides used in classical reference tantalum, reliable evidence for the existence of inde electrodes with the chloride–oxyfluoride melt. pendent forms of tantalum monoxide (TaO) is still The electrolytic processes with accumulation of absent. It can be considered the established fact that products electrodeposited on the cathode were per TaO is formed (often as a thin intermediate layer 2– formed in a sealed electrolyzer in the galvanostatic 30 nm thick) in oxidation and electrooxidation of mode. The cell, as a platinum crucible (30 mm in metallic tantalum to Ta O in various media [1, 2]. 2 5 diameter, 40 mm in height), was placed inside a cylin der
Doklady Chemistry – Springer Journals
Published: Sep 19, 2009
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