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Hugues Duncan, N. Salem, Y. Abu-Lebdeh (2013)
Electrolyte Formulations Based on Dinitrile Solvents for High Voltage Li-Ion BatteriesJournal of The Electrochemical Society, 160
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Electrochemical impedance study of graphite/electrolyte interface formed in LiBOB/PC electrolyteJournal of Power Sources, 143
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Seonbaek Ha, Jung‐Gu Han, Young-Min Song, M. Chun, Sangil Han, Woo-Cheol Shin, N. Choi (2013)
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AlF3 coating of LiNi0.5Mn1.5O4 for high-performance Li-ion batteriesIonics, 17
Lithium bis(oxalate)borate (LiBOB) is a promising salt for lithium-ion batteries. However, it is necessary to exert the electrochemical performance of LiBOB by the appropriate solvent. With dimethyl sulfite (DMS) as mixed solvents, the electrochemical behavior of γ-butyrolactone (GBL) with LiBOB is studied in this paper. It shows that LiBOB-GBL/DMS electrolyte has high oxidation potential (>5.3 V) and satisfactory conductivities. When used in lithium and mesophase carbon microbead cells, the novel electrolyte exhibits not only excellent film-forming characteristics but also low impedances of the interface films. Besides, when used in LiFeO4/Li cells, compared to the cell with the electrolyte system of 1 mol L−1 LiPF6–ethylene carbonate (EC)/dimethyl carbonate (DMC) (1:1, v/v), LiBOB-based electrolyte exhibits several advantages, such as more stable cycle performance at room temperature and higher mean voltage.
Ionics – Springer Journals
Published: Dec 13, 2013
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