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References (41)
-
A Yamada, S-C Chung (2001)
Crystal chemistry of the olivine-type Li(Mn y Fe 1-y )PO4 and (Mn y Fe 1-y )PO4 as possible 4 V cathode materials for lithium batteriesJ Electrochem Soc, 148
-
S. Shi, Lijun Liu, C. Ouyang, Ding-sheng Wang, Zhaoxiang Wang, Liquan Chen, Xuejie Huang (2003)
Enhancement of electronic conductivity of LiFePO4 by cr doping and its identification by first-principles calculationsPhysical Review B, 68
-
Yanzhao Cui, X. Zhao, R. Guo (2010)
Improved electrochemical performance of La0.7Sr0.3MnO3 and carbon co-coated LiFePO4 synthesized by freeze-drying processElectrochimica Acta, 55
-
K. Zaghib, M. Trudeau, A. Guerfi, J. Trottier, A. Mauger, R. Veillette, C. Julien (2012)
New advanced cathode material: LiMnPO4 encapsulated with LiFePO4Journal of Power Sources, 204
-
Seung Oh, Hun‐Gi Jung, C. Yoon, Seung‐Taek Myung, Zonghai Chen, K. Amine, Yang‐Kook Sun (2011)
Enhanced electrochemical performance of carbon–LiMn1−xFexPO4 nanocomposite cathode for lithium-ion batteriesJournal of Power Sources, 196
-
Jian Hong, Feng Wang, Xiao-Liang Wang, J. Graetz (2011)
LiFexMn1―xPO4: A cathode for lithium-ion batteriesJournal of Power Sources, 196
-
H. Yi, Chen Hu, Xiangming He, Hongyun Xu (2015)
Electrochemical performance of LiMnPO4 by Fe and Zn co-doping for lithium-ion batteriesIonics, 21
-
Tao Liu, Jingjing Xu, Binbin Wu, Qingbo Xia, Xiaodong Wu (2013)
Porous LiMn0.7Fe0.3PO4–C prepared by a thermal decomposition method as high performance cathode materials for Li-ion batteriesRSC Advances, 3
-
Ling Wu, Shengkui Zhong, Jiajia Lu, Jie-qun Liu, Fan Lv (2013)
Synthesis of Cr-doped LiMnPO4/C cathode materials by sol–gel combined ball milling method and its electrochemical propertiesIonics, 19
-
S. Martha, J. Grinblat, Ortal Haik, E. Zinigrad, T. Drezen, J. Miners, I. Exnar, A. Kay, B. Markovsky, D. Aurbach (2009)
LiMn(0.8)Fe(0.2)PO(4): an advanced cathode material for rechargeable lithium batteries.Angewandte Chemie, 48 45
-
M. Sahana, S. Vasu, N. Sasikala, S. Anandan, H. Sepehri-Amin, C. Sudakar, R. Gopalan (2014)
Raman spectral signature of Mn-rich nanoscale phase segregations in carbon free LiFe1−xMnxPO4 prepared by hydrothermal techniqueRSC Advances, 4
-
Seung‐Min Oh, S. Oh, C. Yoon, B. Scrosati, K. Amine, Yangfang Sun (2010)
High‐Performance Carbon‐LiMnPO4 Nanocomposite Cathode for Lithium BatteriesAdvanced Functional Materials, 20
-
A. Yamada, Y. Kudo, Kuang-Yu Liu (2001)
Phase Diagram of Li x ( Mn y Fe1 − y ) PO 4 ( 0 ⩽ x , y ⩽ 1 )Journal of The Electrochemical Society, 148
-
H. Shin, Sung Park, H. Jang, K. Chung, W. Cho, Chang Kim, B. Cho (2008)
Rate performance and structural change of Cr-doped LiFePO4/C during cyclingElectrochimica Acta, 53
-
A Yamada, Y Kudo, K-Y Liu (2001)
Phase diagram of Li x Mn y Fe 1−y PO4 (0≤x, y≤1)J ElectrochemSoc, 148
-
Hailiang Wang, Yuan Yang, Yongye Liang, Lifeng Cui, H. Casalongue, Yanguang Li, Guosong Hong, Yi Cui, H. Dai (2011)
LiMn(1-x)Fe(x)PO4 nanorods grown on graphene sheets for ultrahigh-rate-performance lithium ion batteries.Angewandte Chemie, 50 32
-
G Li, H Azuma, M Tohda (2002)
Optimized LiMn y Fe1-y PO4 as the cathode for lithium batteriesJ Electrochem Soc, 149
-
A. Padhi, K. Nanjundaswamy, J. Goodenough (1997)
Phospho‐olivines as Positive‐Electrode Materials for Rechargeable Lithium BatteriesJournal of The Electrochemical Society, 144
-
Y. Gan, Cheng Chen, Jiali Liu, P. Bian, H. Hao, A. Yu (2015)
Enhancing the performance of LiMnPO4/C composites through Cr dopingJournal of Alloys and Compounds, 620
-
Li'e Li, Jing Liu, L. Chen, Huayun Xu, Jian Yang, Yitai Qian (2013)
Effect of different carbon sources on the electrochemical properties of rod-like LiMnPO4–C nanocompositesRSC Advances, 3
-
S. Ong, V. Chevrier, G. Ceder (2011)
Comparison of Small Polaron Migration and Phase Separation in Olivine LiMnPO₄ and LiFePO₄ using Hybrid Density Functional Theory -
L. Damen, F. Giorgio, S. Monaco, Federico Veronesi, M. Mastragostino (2012)
Synthesis and characterization of carbon-coated LiMnPO4 and LiMn1−xFexPO4 (x = 0.2, 0.3) materials for lithium-ion batteriesJournal of Power Sources, 218
-
J Liu, X Liu, T Huang, A Yu (2012)
Kinetics and electrochemical studies of Fe-substituted LiMnPO4Int J Electrochem Sci, 7
-
J. Yoshida, M. Stark, J. Holzbock, N. Hüsing, Shinji Nakanishi, H. Iba, H. Abe, M. Naito (2013)
Analysis of the size effect of LiMnPO4 particles on the battery properties by using STEM-EELSJournal of Power Sources, 226
-
A. Yamada, Sai-Cheong Chung (2001)
Crystal Chemistry of the Olivine-Type Li ( Mn y Fe1 − y ) PO 4 and ( Mn y Fe1 − y ) PO 4 as Possible 4 V Cathode Materials for Lithium BatteriesJournal of The Electrochemical Society, 148
-
R. Hagen, Henning Lorrmann, K. Möller, S. Mathur (2012)
Electrospun LiFe1−yMnyPO4/C Nanofiber Composites as Self‐Supporting Cathodes in Li‐Ion BatteriesAdvanced Energy Materials, 2
-
B Zhang, X Wang, Z Liu, H Li, X Huang (2010)
Enhanced electrochemical performances of carbon coated mesoporous LiFe0.2Mn0.8PO4JElectrochem. Soc, 157
-
Jun Zong, Qingwen Peng, Jinpeng Yu, Xingjiang Liu (2013)
Novel precursor of Mn(PO3(OH))·3H2O for synthesizing LiMn0.5Fe0.5PO4 cathode materialJournal of Power Sources, 228
-
Bin Zhang, Xiaojiang Wang, Zhaojun Liu, Hong Li, Xuejie Huang (2010)
Enhanced Electrochemical Performances of Carbon Coated Mesoporous LiFe0.2Mn0.8PO4Journal of The Electrochemical Society, 157
-
I. Jang, H. Lim, S. Lee, K. Karthikeyan, V. Aravindan, K. Kang, W. Yoon, Woo-Seok Cho, Yun‐Sung Lee (2010)
Preparation of LiCoPO4 and LiFePO4 coated LiCoPO4 materials with improved battery performanceJournal of Alloys and Compounds, 497
-
S. Shang, Wang Yuji, Z. Mei, X. Hui, Zi-kui Liu (2012)
Lattice dynamics, thermodynamics, and bonding strength of lithium-ion battery materials LiMPO4 (M = Mn, Fe, Co, and Ni): a comparative first-principles studyJournal of Materials Chemistry, 22
-
Zhuo Tan, P. Gao, Fu-quan Cheng, Hongjun Luo, Jitao Chen, Henghui Zhou, Songting Tan (2011)
HIGH POWER PERFORMANCE OF MULTICOMPONENT OLIVINE CATHODE MATERIAL FOR LITHIUM-ION BATTERIESFunctional Materials Letters, 04
-
Lulu Zhang, Song Duan, Gang. Peng, G. Liang, Feng Zou, Yunhui Huang (2013)
Novel synthesis of low carbon-coated Li3V2(PO4)3 cathode material for lithium-ion batteriesJournal of Alloys and Compounds, 570
-
Deyu Wang, C. Ouyang, T. Drezen, I. Exnar, A. Kay, N. Kwon, P. Gouérec, J. Miners, Mingkui Wang, M. Grätzel (2010)
Improving the Electrochemical Activity of LiMnPO4 Via Mn-Site SubstitutionJournal of The Electrochemical Society, 157
-
Guohua Li, Hideto Azuma, Masayuki Tohda (2002)
Optimized LiMn y Fe1 − y PO 4 as the Cathode for Lithium BatteriesJournal of The Electrochemical Society, 149
-
Junsu Park, Won Moon, Gil-Pyo Kim, Inho Nam, Soomin Park, Younghun Kim, J. Yi (2013)
Three-dimensional aligned mesoporous carbon nanotubes filled with Co3O4 nanoparticles for Li-ion battery anode applicationsElectrochimica Acta, 105
-
J. Xiang, J. Tu, Y. Qiao, Xiaolong Wang, J. Zhong, Di Zhang, C. Gu (2011)
Electrochemical Impedance Analysis of a Hierarchical CuO Electrode Composed of Self-Assembled NanoplatesJournal of Physical Chemistry C, 115
-
H. Fang, H. Yi, Chen Hu, Bin Yang, Yaochun Yao, Wenhui Ma, Yong-nian Dai (2012)
Effect of Zn doping on the performance of LiMnPO4 cathode for lithium ion batteriesElectrochimica Acta, 71
-
Yurong Zhang, Yanyan Zhao, L. Deng (2012)
Enhanced electrochemical properties of LiMnPO4/C via doping with CuIonics, 18
-
V. Aravindan, J. Gnanaraj, Yun‐Sung Lee, S. Madhavi (2013)
LiMnPO4 - A next generation cathode material for lithium-ion batteriesJournal of Materials Chemistry, 1
-
Ch. Reddy, M. Chen, W. Jin, Q. Zhu, W. Chen, S. Mho (2007)
Characterization of (PVDF + LiFePO4) solid polymer electrolyteJournal of Applied Electrochemistry, 37
- Publisher
- Springer Journals
- Copyright
- Copyright © 2016 by Springer-Verlag Berlin Heidelberg
- Subject
- Chemistry; Electrochemistry; Renewable and Green Energy; Optical and Electronic Materials; Condensed Matter Physics; Energy Storage
- ISSN
- 0947-7047
- eISSN
- 1862-0760
- DOI
- 10.1007/s11581-015-1633-6
- Publisher site
- See Article on Publisher Site
Abstract
A comparison of electrochemical performance between LiFe0.4Mn0.595Cr0.005PO4/C and LiMnPO4/C cathode materials was conducted in this paper. The cathode samples were synthesized by a nano-milling-assisted solid-state process using caramel as carbon sources. The prepared samples were investigated by XRD, SEM, TEM, energy-dispersive X-ray spectroscopy (EDAX), powder conductivity test (PCT), carbon-sulfur analysis, electrochemical impedance spectroscopy (EIS), and galvanostatic charge-discharge cycling. The results showed that LiFe0.4Mn0.595Cr0.005PO4/C exhibited high specific capacity and high energy density. The initial discharge capacity of LiFe0.4Mn0.595Cr0.005PO4/C was 163.6 mAh g−1 at 0.1C (1C = 160 mA g−1), compared to 112.3 mAh g−1 for LiMnPO4/C. Moreover, the Fe/Cr-substituted sample showed good cycle stability and rate performance. The capacity retention of LiFe0.4Mn0.595Cr0.005PO4/C was 98.84 % over 100 charge-discharge cycles, while it was only 86.64 % for the pristine LiMnPO4/C. These results indicated that Fe/Cr substitution enhanced the electronic conductivity for the prepared sample and facilitated the Li+ diffusion in the structure. Furthermore, LiFe0.4Mn0.595Cr0.005PO4/C composite presented high energy density (606 Wh kg−1) and high power density (574 W kg−1), thus suggested great potential application in lithium ion batteries (LIBs).
Journal
Ionics – Springer Journals
Published: Jan 21, 2016