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ISSN 00125008, Doklady Chemistry, 2013, Vol. 451, Part 2, pp. 203–206. © Pleiades Publishing, Ltd., 2013. Original Russian Text © S.V. Basenko, A.S. Soldatenko, M.G. Voronkov, 2013, published in Doklady Akademii Nauk, 2013, Vol. 451, No. 5, pp. 528–532. CHEMISTRY Efficient Method for the Synthesis of Symmetrical α,ωDichloro1,1,3,3tetraorganyldisiloxanes S. V. Basenko, A. S. Soldatenko, and Academician M. G. Voronkov Received March 13, 2013 DOI: 10.1134/S001250081308003X α,ωDichloroorganyldisiloxanes (DCSs) are used electrical engineering, pharmacy, food processing as precursors in preparing linear and cyclic siloxanes industry, cosmetics, and medicine [1–3]. and polysiloxanes showing biological activity; adhe From the 1940s, numerous studies of the synthesis sive, hydrophobic, dielectric and properties; durability of DCSs have been reported. The main method of their and ability to operate under extreme conditions (tem preparation is the controlled hydrolysis of diorganyldi perature, humidity, etc.). They find a wide application in aerospace, automotive, and chemical industry; chlorosilanes or diorganylchlorosilanes [1, 4–7]. R R + 2(n –1)HCl nRR SiCl + (n –1)H O Cl Si O Si Cl 2 2 1 1 R R n –1 (R = H, Me, Ph, Cl; R = H, Me, Vin, Ph, αNp, C H SiMe Cl; n = 2–5). 6 4 2 They
Doklady Chemistry – Springer Journals
Published: Aug 23, 2013
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