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- Publisher
- Springer Journals
- Copyright
- Copyright © 2011 by Springer-Verlag
- Subject
- Chemistry; Renewable and Green Energy; Electrochemistry; Condensed Matter Physics; Optical and Electronic Materials
- ISSN
- 0947-7047
- eISSN
- 1862-0760
- DOI
- 10.1007/s11581-011-0651-2
- Publisher site
- See Article on Publisher Site
Abstract
The sensing characteristics of an amperometric NOx sensor with yttria-stabilized zirconia and a La-based perovskite-type oxide sensing electrode were examined. La1-xSrxMO3 (M = Co, Mn, x = 0, 0.2, 0.4, 0.6) were synthesized using the spray pyrolysis method. The NO2 response of a sensor fabricated with La1-xSrxMnO3 increased with increasing amount of Sr, and the trend was in contrast to that of the sensors fabricated with La1-xSrxCoO3. LaSr0.2MnO3 was determined to be the most appropriate material for the sensor in terms of a high NO2 response and low O2 current. In order to discuss the effects of Sr addition to La-based perovskite oxides for the sensor, NO adsorption and desorption properties of oxides and the relationship between the oxidation number of the B-site cation and Sr substitution were examined using temperature-programmed desorption and X-ray photoelectron spectroscopy, respectively.
Journal
Ionics – Springer Journals
Published: Dec 14, 2011