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P. Dean (1973)
A 19F Nuclear Magnetic Resonance Study of Polymeric Fluoroanions of Tin(IV) and Titanium(IV)Canadian Journal of Chemistry, 51
A. Herzog, Feng Liu, H. Roesky, A. Demšar, K. Keller, M. Noltemeyer, F. Pauer (1994)
Trimethyltin Fluoride: A New Fluorinating Reagent for the Preparation of Organometallic FluoridesOrganometallics, 13
Doklady Chemistry, Vol. 386, Nos. 4–6, 2002, pp. 280–284. Translated from Doklady Akademii Nauk, Vol. 386, No. 6, 2002, pp. 779–784. Original Russian Text Copyright © 2002 by Il’in, Nikiforov, Buslaev. CHEMISTRY Dimeric Fluoro Chloro Anions (m-F )[Ti F Cl ] , New 3 2 6 – n n Representatives of Mixed-Halide Titanium Compounds: Composition, Structure, and Isomerism E. G. Il’in, G. B. Nikiforov, and Academician Yu. A. Buslaev Received June 25, 2002 In low-polarity solvents with weak donor properties, the octahedral moieties of dimeric [Ti Cl F ] anions 2 n 9 Ð n the coordinative saturation of Ti(IV) is attained owing with three fluorine bridges and one to three terminal flu- to bridging halide ions. Because the bridging bonds are orine atoms. The signals in the range 261–270 ppm the weakest, their presence radically alters the reactiv- arise from the moieties containing three terminal fluo- ity of titanium complexes. In this context, synthesis of rine atoms. The strongest line at 265 ppm arises from new representatives of mixed titanium halides contain- the dimeric anion [Ti F ] (1) (Table 1), which incorpo- 2 9 ing bridging halide ions is of interest to both the chem- rates two
Doklady Chemistry – Springer Journals
Published: Oct 10, 2004
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