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Dimeric Fluoro Chloro Anions (μ-F3)[Ti2F6 – n Cl n ]–, New Representatives of Mixed-Halide Titanium Compounds: Composition, Structure, and Isomerism

Dimeric Fluoro Chloro Anions (μ-F3)[Ti2F6 – n Cl n ]–, New Representatives of Mixed-Halide... Doklady Chemistry, Vol. 386, Nos. 4–6, 2002, pp. 280–284. Translated from Doklady Akademii Nauk, Vol. 386, No. 6, 2002, pp. 779–784. Original Russian Text Copyright © 2002 by Il’in, Nikiforov, Buslaev. CHEMISTRY Dimeric Fluoro Chloro Anions (m-F )[Ti F Cl ] , New 3 2 6 – n n Representatives of Mixed-Halide Titanium Compounds: Composition, Structure, and Isomerism E. G. Il’in, G. B. Nikiforov, and Academician Yu. A. Buslaev Received June 25, 2002 In low-polarity solvents with weak donor properties, the octahedral moieties of dimeric [Ti Cl F ] anions 2 n 9 Ð n the coordinative saturation of Ti(IV) is attained owing with three fluorine bridges and one to three terminal flu- to bridging halide ions. Because the bridging bonds are orine atoms. The signals in the range 261–270 ppm the weakest, their presence radically alters the reactiv- arise from the moieties containing three terminal fluo- ity of titanium complexes. In this context, synthesis of rine atoms. The strongest line at 265 ppm arises from new representatives of mixed titanium halides contain- the dimeric anion [Ti F ] (1) (Table 1), which incorpo- 2 9 ing bridging halide ions is of interest to both the chem- rates two http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Doklady Chemistry Springer Journals

Dimeric Fluoro Chloro Anions (μ-F3)[Ti2F6 – n Cl n ]–, New Representatives of Mixed-Halide Titanium Compounds: Composition, Structure, and Isomerism

Doklady Chemistry , Volume 386 (6) – Oct 10, 2004

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References (2)

Publisher
Springer Journals
Copyright
Copyright © 2002 by MAIK “Nauka/Interperiodica”
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
0012-5008
eISSN
1608-3113
DOI
10.1023/A:1020743408305
Publisher site
See Article on Publisher Site

Abstract

Doklady Chemistry, Vol. 386, Nos. 4–6, 2002, pp. 280–284. Translated from Doklady Akademii Nauk, Vol. 386, No. 6, 2002, pp. 779–784. Original Russian Text Copyright © 2002 by Il’in, Nikiforov, Buslaev. CHEMISTRY Dimeric Fluoro Chloro Anions (m-F )[Ti F Cl ] , New 3 2 6 – n n Representatives of Mixed-Halide Titanium Compounds: Composition, Structure, and Isomerism E. G. Il’in, G. B. Nikiforov, and Academician Yu. A. Buslaev Received June 25, 2002 In low-polarity solvents with weak donor properties, the octahedral moieties of dimeric [Ti Cl F ] anions 2 n 9 Ð n the coordinative saturation of Ti(IV) is attained owing with three fluorine bridges and one to three terminal flu- to bridging halide ions. Because the bridging bonds are orine atoms. The signals in the range 261–270 ppm the weakest, their presence radically alters the reactiv- arise from the moieties containing three terminal fluo- ity of titanium complexes. In this context, synthesis of rine atoms. The strongest line at 265 ppm arises from new representatives of mixed titanium halides contain- the dimeric anion [Ti F ] (1) (Table 1), which incorpo- 2 9 ing bridging halide ions is of interest to both the chem- rates two

Journal

Doklady ChemistrySpringer Journals

Published: Oct 10, 2004

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