Access the full text.
Sign up today, get DeepDyve free for 14 days.
J. Sansom, D. Richings, P. Slater (2001)
A powder neutron diffraction study of the oxide-ion-conducting apatite-type phases, La9.33Si6O26 and La8Sr2Si6O26Solid State Ionics, 139
Peng-nian Huang, A. Petric (1996)
Superior Oxygen Ion Conductivity of Lanthanum Gallate Doped with Strontium and MagnesiumJournal of The Electrochemical Society, 143
A. Shaula, V. Kharton, J. Waerenborgh, D. Rojas, E. Tsipis, N. Vyshatko, M. Patrakeev, F. Marques (2004)
Transport properties and Mössbauer spectra of Fe-substituted La10−x(Si,Al)6O26 apatitesMaterials Research Bulletin, 39
J. McFarlane, Sven Barth, M. Swaffer, J. Sansom, Peter Slater (2002)
Synthesis and conductivities of the apatite-type systems, La9.33+xSi6−yMyO26+z (M=Co, Fe, Mn) and La8Mn2Si6O26Ionics, 8
J. Drennan, V. Zelizko, D. Hay, F. Ciacchi, S. Rajendran, S. Badwal (1997)
Characterisation, conductivity and mechanical properties of theoxygen-ion conductor La0.9Sr0.1Ga0.8Mg0.2O3-xJournal of Materials Chemistry, 7
M. Islam (2002)
Computer modelling of defects and transport in perovskite oxidesSolid State Ionics, 154
M. Martín-Sedeño, E. Losilla, L. León-Reina, S. Bruque, D. Marrero-López, P. Núñez, M. Aranda (2004)
Enhancement of Oxide Ion Conductivity in Cuspidine-Type MaterialsChemistry of Materials, 16
L. León-Reina, E. Losilla, M. Martínez-Lara, S. Bruque, A. Llobet, D. Sheptyakov, M. Aranda (2005)
Interstitial oxygen in oxygen-stoichiometric apatites{Journal of Materials Chemistry, 15
V. Kharton, A. Shaula, N. Vyshatko, F. Marques (2003)
Electron-hole transport in (La0.9Sr0.1)0.98Ga0.8Mg0.2O3−δ electrolyte: effects of ceramic microstructureElectrochimica Acta, 48
J. Kilner, B. Steele (1981)
5 – Mass Transport in Anion-Deficient Fluorite Oxides
V. Kharton, F. Marques, A. Atkinson (2004)
Transport properties of solid oxide electrolyte ceramics: a brief reviewSolid State Ionics, 174
S. Nakayama, Tatsuya Kageyama, H. Aono, Y. Sadaoka (1995)
Ionic conductivity of lanthanoid silicates, Ln10(SiO4)6O3(Ln = La, Nd, Sm, Gd, Dy, Y, Ho, Er and Yb)Journal of Materials Chemistry, 5
A. Chesnaud, O. Joubert, M. Caldes, Samrat Ghosh, Y. Piffard, L. Brohan (2004)
Cuspidine-like compounds Ln4[Ga2(1-x)Ge2xO7+x□1-x]O2 (Ln = La, Nd, Gd; x ≤ 0.4)Chemistry of Materials, 16
S. Tao, J. Irvine (2001)
Preparation and characterisation of apatite-type lanthanum silicates by a sol-gel processMaterials Research Bulletin, 36
T. Etsell, S. Flengas (1970)
Electrical properties of solid oxide electrolytesChemical Reviews, 70
E. Subbarao, H. Maiti (1984)
Solid electrolytes with oxygen ion conductionSolid State Ionics, 11
J. Kilner, R. Brook (1982)
A study of oxygen ion conductivity in doped non-stoichiometric oxidesSolid State Ionics, 6
A. Shaula, V. Kharton, F. Marques (2005)
Oxygen ionic and electronic transport in apatite-type La10−x(Si,Al)6O26±δJournal of Solid State Chemistry, 178
S. Nakayama, M. Sakamoto (1998)
Electrical properties of new type high oxide ionic conductor RE10Si6O27 (RE = La, Pr, Nd, Sm, Gd, Dy)Journal of The European Ceramic Society, 18
V. Kharton, A. Shaula, M. Patrakeev, J. Waerenborgh, D. Rojas, N. Vyshatko, E. Tsipis, A. Yaremchenko, F. Marques (2004)
Oxygen Ionic and Electronic Transport in Apatite-Type Solid ElectrolytesJournal of The Electrochemical Society, 151
J. Stevenson, T. Armstrong, D. Mccready, L. Pederson, W. Weber (1997)
Processing and Electrical Properties of Alkaline Earth‐Doped Lanthanum GallateJournal of The Electrochemical Society, 144
T. Ishihara, H. Arikawa, T. Akbay, H. Nishiguchi, Y. Takita (2001)
Nonstoichiometric La(2 - x)GeO(5 - delta) monoclinic oxide as a new fast oxide ion conductor.Journal of the American Chemical Society, 123 2
S. Kramer, H. Tuller (1995)
A novel titanate-based oxygen ion conductor: Gd2Ti2O7Solid State Ionics, 82
Stephen Skinner, John Kilner (2003)
Oxygen ion conductorsMaterials Today, 6
R. Baker, B. Gharbage, F. Marques (1997)
Ionic and Electronic Conduction in Fe and Cr Doped ( La , Sr ) GaO3 − ΔJournal of The Electrochemical Society, 144
J. Tolchard, M. Islam, Peter Slater (2003)
Defect chemistry and oxygen ion migration in the apatite-type materials La9.33Si6O26 and La8Sr2Si6O26Journal of Materials Chemistry, 13
V. Kharton, A. Viskup, E. Naumovich, N. Lapchuk (1997)
Mixed electronic and ionic conductivity of LaCo(M)O3 (M = Ga, Cr, Fe or Ni). I. Oxygen transport in perovskites LaCoO3-LaGaO3Solid State Ionics, 104
T. Ishihara, H. Matsuda, Y. Takita (1994)
Doped LaGaO3 Perovskite Type Oxide as a New Oxide Ionic ConductorJournal of the American Chemical Society, 116
M. Lacerda, J. Irvine, F. Glasser, A. West (1988)
High oxide ion conductivity in Ca12Al14O33Nature, 332
V. Kharton, A. Viskup, F. Figueiredo, E. Naumovich, A. Yaremchenko, F. Marques (2001)
Electron–hole conduction in Pr-doped Ce(Gd)O2−δ by faradaic efficiency and emf measurementsElectrochimica Acta, 46
M. Feng, J. Goodenough (1995)
A Superior Oxide-Ion Electrolyte.ChemInform, 26
H. Okudera, Y. Masubuchi, S. Kikkawa, A. Yoshiasa (2005)
Structure of oxide ion-conducting lanthanum oxyapatite, La9.33(SiO4)6O2Solid State Ionics, 176
O. Joubert, A. Magrez, A. Chesnaud, M. Caldes, V. Jayaraman, Y. Piffard, L. Brohan (2002)
Structural and transport properties of a new class of oxide ion conductors: Nd4[Ga2(1−x)M2xO7+x□1−x]O2 (M=Ti, Ge)Solid State Sciences, 4
T. Ishihara, Masakazu Higuchi, Haruyoshi Furutani, T. Fukushima, H. Nishiguchi, Y. Takita (1997)
Potentiometric Oxygen Sensor Operable in Low Temperature by Applying LaGaO3‐Based Oxide for ElectrolyteJournal of The Electrochemical Society, 144
F. Marques, G. Wirtz (1991)
Electrical Properties of Ceria-Doped YttriaJournal of the American Ceramic Society, 74
B. Calès, J. Baumard (1984)
Mixed conduction and defect structure of ZrO/sub 2/-CeO/sub 2/-Y/sub 2/O/sub 3/ solid solutionsJournal of The Electrochemical Society, 131
M. Mori, T. Abe, H. Itoh, O. Yamamoto, Y. Takeda, T. Kawahara (1994)
Cubic-stabilized zirconia and alumina composites as electrolytes in planar type solid oxide fuel cellsSolid State Ionics, 74
P. Anderson, G. Mather, F. Marques, D. Sinclair, A. West (1999)
Synthesis and characterisation of La0·95Sr0·05GaO3−δ, La0·95Sr0·05AlO3−δ and Y0·95Sr0·05AlO3−δJournal of The European Ceramic Society, 19
In the past ten years a series of developments in the field of materials with dominant oxygen ion conduction introduced a variety of new systems. The most relevant aspect is a shift from ionic transport mechanisms based on the motion of oxygen vacancies, to mechanisms based on mobile oxygen interstitials. In parallel, structures identified with dominant oxygen ion conduction moved from the relatively simple fluorite related ones to more complex materials, namely with the apatite-type and related structures, including coexistence of ionic and covalent bonding. This shift is understood as a major development, opening a wide range of alternative solutions for further exploitation.
Ionics – Springer Journals
Published: May 16, 2006
Read and print from thousands of top scholarly journals.
Already have an account? Log in
Bookmark this article. You can see your Bookmarks on your DeepDyve Library.
To save an article, log in first, or sign up for a DeepDyve account if you don’t already have one.
Copy and paste the desired citation format or use the link below to download a file formatted for EndNote
Access the full text.
Sign up today, get DeepDyve free for 14 days.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.