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Crystal structure of Sr(AsUO 6 ) 2 · 8H 2 O

Crystal structure of Sr(AsUO 6 ) 2 · 8H 2 O Abstract The crystal structure of the compound Sr(AsUO6)2 · 8H2O is determined by X-ray diffraction analysis (monoclinic system, sp. gr. Pc, unit-cell parameters a = 7.154(1) Å, b = 7.101(1) Å, c = 18.901(7) Å, β = 92.67(2)°, Z = 2). The structure is built by (001)-parallel [AsUO6]− layers formed by flattened square UO6 bipyramids and AsO4 tetrahedra. The neighboring layers are connected via SrO8 square antiprisms. The cavities of the polyhedral framework thus formed are occupied by H2O molecules. The displacements of the anion complexes by a half-translation with respect to one another along only one lattice period is a characteristic feature of this polymorphous modification of the uran-mica group. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Crystallography Reports Springer Journals

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References (9)

Publisher
Springer Journals
Copyright
2003 MAIK "Nauka/Interperiodica"
ISSN
1063-7745
eISSN
1562-689X
DOI
10.1134/1.1564197
Publisher site
See Article on Publisher Site

Abstract

Abstract The crystal structure of the compound Sr(AsUO6)2 · 8H2O is determined by X-ray diffraction analysis (monoclinic system, sp. gr. Pc, unit-cell parameters a = 7.154(1) Å, b = 7.101(1) Å, c = 18.901(7) Å, β = 92.67(2)°, Z = 2). The structure is built by (001)-parallel [AsUO6]− layers formed by flattened square UO6 bipyramids and AsO4 tetrahedra. The neighboring layers are connected via SrO8 square antiprisms. The cavities of the polyhedral framework thus formed are occupied by H2O molecules. The displacements of the anion complexes by a half-translation with respect to one another along only one lattice period is a characteristic feature of this polymorphous modification of the uran-mica group.

Journal

Crystallography ReportsSpringer Journals

Published: Mar 1, 2003

Keywords: Crystallography and Scattering Methods

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