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Crystal and Molecular Structure of N-(Trifluorosilylmethyl)phthalimide

Crystal and Molecular Structure of N-(Trifluorosilylmethyl)phthalimide Doklady Chemistry, Vol. 393, Nos. 4–6, 2003, pp. 275–278. Translated from Doklady Akademii Nauk, Vol. 393, No. 4, 2003, pp. 493–496. Original Russian Text Copyright © 2003 by Voronkov, Zel’bst, Kashaev, Katkevich, Fundamenskii, Bolgova, Trofimova, Albanov, Chernov, Pestunovich. CHEMISTRY Crystal and Molecular Structure of N-(Trifluorosilylmethyl)phthalimide Academician M. G. Voronkov*, E. A. Zel’bst**, A. A. Kashaev**, Yu. V. Katkevich**, V. S. Fundamenskii**, Yu. I. Bolgova*, O. M. Trofimova*, A. I. Albanov*, N. F. Chernov*, and V. A. Pestunovich* Received July 17, 2003 In the 1970s, a new class of stable compounds of F pentacoordinate silicon was discovered in the labora- Si tory headed by M.G. Voronkov. Their general formula was R O Z = O, S, NR'; As distinct from almost all known dragonoids, TFSP Si R, R' = organic substituents. has two competing, completely identical carbonyl groups. The oxygen atom in each of these groups is capable of forming an intramolecular coordinate link These compounds were named dragonoids because OSi with the silicon atom, the latter becoming pen- their structure looked like the alchemists’ favorite sym- tacoordinate. This makes it possible to suppose the bol, a dragon devouring its tail. A review of these com- pounds appeared in 1991 http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Doklady Chemistry Springer Journals

Crystal and Molecular Structure of N-(Trifluorosilylmethyl)phthalimide

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Publisher
Springer Journals
Copyright
Copyright © 2003 by MAIK “Nauka/Interperiodica”
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
0012-5008
eISSN
1608-3113
DOI
10.1023/B:DOCH.0000010329.29516.f6
Publisher site
See Article on Publisher Site

Abstract

Doklady Chemistry, Vol. 393, Nos. 4–6, 2003, pp. 275–278. Translated from Doklady Akademii Nauk, Vol. 393, No. 4, 2003, pp. 493–496. Original Russian Text Copyright © 2003 by Voronkov, Zel’bst, Kashaev, Katkevich, Fundamenskii, Bolgova, Trofimova, Albanov, Chernov, Pestunovich. CHEMISTRY Crystal and Molecular Structure of N-(Trifluorosilylmethyl)phthalimide Academician M. G. Voronkov*, E. A. Zel’bst**, A. A. Kashaev**, Yu. V. Katkevich**, V. S. Fundamenskii**, Yu. I. Bolgova*, O. M. Trofimova*, A. I. Albanov*, N. F. Chernov*, and V. A. Pestunovich* Received July 17, 2003 In the 1970s, a new class of stable compounds of F pentacoordinate silicon was discovered in the labora- Si tory headed by M.G. Voronkov. Their general formula was R O Z = O, S, NR'; As distinct from almost all known dragonoids, TFSP Si R, R' = organic substituents. has two competing, completely identical carbonyl groups. The oxygen atom in each of these groups is capable of forming an intramolecular coordinate link These compounds were named dragonoids because OSi with the silicon atom, the latter becoming pen- their structure looked like the alchemists’ favorite sym- tacoordinate. This makes it possible to suppose the bol, a dragon devouring its tail. A review of these com- pounds appeared in 1991

Journal

Doklady ChemistrySpringer Journals

Published: Oct 5, 2004

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