Access the full text.
Sign up today, get DeepDyve free for 14 days.
V. Pestunovich, S. Kirpichenko, M. Voronkov (1998)
The Chemistry of Organic Silicon Compounds
Doklady Chemistry, Vol. 386, Nos. 1–3, 2002, pp. 233–237. Translated from Doklady Akademii Nauk, Vol. 386, No. 1, 2002, pp. 56–60. Original Russian Text Copyright © 2002 by Voronkov, Zelbst, Kashaev, Katkevich, Fundamenskii, Bolgova, Trofimova, Chernov. CHEMISTRY Crystal and Molecular Structure of N-(1-Silatranylmethyl)pyrrole Academician M. G. Voronkov*, E. A. Zelbst**, A. A. Kashaev**, Yu. V. Katkevich**, V. S. Fundamenskii**, Yu. I. Bolgova*, O. M. Trofimova*, and N. F. Chernov* Received May 7, 2002 In the last few years, we have studied the chemistry metric parameters of the pyrrole ring in molecules II of N-(silatranylmethyl)azoles to elucidate the influence and III are close to each other. This indicates that the of this super-electron-donating substituent on the stere- substitution of a methyl group for the hydrogen atom at oelectronic structure and reactivity of such nitrogen- the nitrogen atom virtually does not change the geom- containing heterocycles [1]. To continue these investi- etry of the pyrrole ring. The bond lengths and bond gations, we have synthesized for the first time N-(1-sil- angles in molecules I, II, and III are compiled in Table 3. atranylmethyl)pyrrole (CH) NCH Si(OCH CH ) N (I) 4 2 2 2 3 In molecule I, all the endocyclic
Doklady Chemistry – Springer Journals
Published: Oct 10, 2004
Read and print from thousands of top scholarly journals.
Already have an account? Log in
Bookmark this article. You can see your Bookmarks on your DeepDyve Library.
To save an article, log in first, or sign up for a DeepDyve account if you don’t already have one.
Copy and paste the desired citation format or use the link below to download a file formatted for EndNote
Access the full text.
Sign up today, get DeepDyve free for 14 days.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.