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Crystal and Molecular Structure of N-(1-Silatranylmethyl)pyrrole

Crystal and Molecular Structure of N-(1-Silatranylmethyl)pyrrole Doklady Chemistry, Vol. 386, Nos. 1–3, 2002, pp. 233–237. Translated from Doklady Akademii Nauk, Vol. 386, No. 1, 2002, pp. 56–60. Original Russian Text Copyright © 2002 by Voronkov, Zelbst, Kashaev, Katkevich, Fundamenskii, Bolgova, Trofimova, Chernov. CHEMISTRY Crystal and Molecular Structure of N-(1-Silatranylmethyl)pyrrole Academician M. G. Voronkov*, E. A. Zelbst**, A. A. Kashaev**, Yu. V. Katkevich**, V. S. Fundamenskii**, Yu. I. Bolgova*, O. M. Trofimova*, and N. F. Chernov* Received May 7, 2002 In the last few years, we have studied the chemistry metric parameters of the pyrrole ring in molecules II of N-(silatranylmethyl)azoles to elucidate the influence and III are close to each other. This indicates that the of this super-electron-donating substituent on the stere- substitution of a methyl group for the hydrogen atom at oelectronic structure and reactivity of such nitrogen- the nitrogen atom virtually does not change the geom- containing heterocycles [1]. To continue these investi- etry of the pyrrole ring. The bond lengths and bond gations, we have synthesized for the first time N-(1-sil- angles in molecules I, II, and III are compiled in Table 3. atranylmethyl)pyrrole (CH) NCH Si(OCH CH ) N (I) 4 2 2 2 3 In molecule I, all the endocyclic http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Doklady Chemistry Springer Journals

Crystal and Molecular Structure of N-(1-Silatranylmethyl)pyrrole

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References (1)

Publisher
Springer Journals
Copyright
Copyright © 2002 by MAIK "Nauka/Interperiodica"
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
0012-5008
eISSN
1608-3113
DOI
10.1023/A:1020348000726
Publisher site
See Article on Publisher Site

Abstract

Doklady Chemistry, Vol. 386, Nos. 1–3, 2002, pp. 233–237. Translated from Doklady Akademii Nauk, Vol. 386, No. 1, 2002, pp. 56–60. Original Russian Text Copyright © 2002 by Voronkov, Zelbst, Kashaev, Katkevich, Fundamenskii, Bolgova, Trofimova, Chernov. CHEMISTRY Crystal and Molecular Structure of N-(1-Silatranylmethyl)pyrrole Academician M. G. Voronkov*, E. A. Zelbst**, A. A. Kashaev**, Yu. V. Katkevich**, V. S. Fundamenskii**, Yu. I. Bolgova*, O. M. Trofimova*, and N. F. Chernov* Received May 7, 2002 In the last few years, we have studied the chemistry metric parameters of the pyrrole ring in molecules II of N-(silatranylmethyl)azoles to elucidate the influence and III are close to each other. This indicates that the of this super-electron-donating substituent on the stere- substitution of a methyl group for the hydrogen atom at oelectronic structure and reactivity of such nitrogen- the nitrogen atom virtually does not change the geom- containing heterocycles [1]. To continue these investi- etry of the pyrrole ring. The bond lengths and bond gations, we have synthesized for the first time N-(1-sil- angles in molecules I, II, and III are compiled in Table 3. atranylmethyl)pyrrole (CH) NCH Si(OCH CH ) N (I) 4 2 2 2 3 In molecule I, all the endocyclic

Journal

Doklady ChemistrySpringer Journals

Published: Oct 10, 2004

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