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Copper(II) organic compounds as intermediates of photochemical transformations of quaternary ammonium tetrachlorocuprates

Copper(II) organic compounds as intermediates of photochemical transformations of quaternary... ISSN 0012-5008, Doklady Chemistry, 2008, Vol. 421, Part 2, pp. 171–174. © Pleiades Publishing, Ltd., 2008. Original Russian Text © E.N. Golubeva, A.V. Lobanov, V.I. Pergushov, N.A. Chumakova, A.I. Kokorin, 2008, published in Doklady Akademii Nauk, 2008, Vol. 421, No. 5, pp. 630–633. CHEMISTRY Copper(II) Organic Compounds as Intermediates of Photochemical Transformations of Quaternary Ammonium Tetrachlorocuprates a a a a b E. N. Golubeva , A. V. Lobanov , V. I. Pergushov , N. A. Chumakova , and A. I. Kokorin Presented by Academician A.L. Buchachenko February 5, 2008 Received February 11, 2008 DOI: 10.1134/S0012500808080016 Stable organometallic compounds with a Cu(II)–C σ and bimolecular processes [3] bond have not been described [1]. Pulse radiolysis and + + 2CuR 2Cu + R , photolysis of divalent copper salts in aqueous solutions [2, 3] and in n-donor solvents [4] gave short-lived copper + + 2+ complexes with organic radicals in which the copper oxi- CuR + H O Cu + RH + H O, 3 2 dation state was presumably two. Dissociation [2] were considered as the key routes for the destruction of + + • CuR Cu + R these complexes. 3.0 405 nm 1.2 1.0 2.5 0.8 0.6 2.0 http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Doklady Chemistry Springer Journals

Copper(II) organic compounds as intermediates of photochemical transformations of quaternary ammonium tetrachlorocuprates

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References (5)

Publisher
Springer Journals
Copyright
Copyright © 2008 by MAIK Nauka
Subject
Chemistry; Industrial Chemistry/Chemical Engineering; Chemistry/Food Science, general
ISSN
0012-5008
eISSN
1608-3113
DOI
10.1134/S0012500808080016
Publisher site
See Article on Publisher Site

Abstract

ISSN 0012-5008, Doklady Chemistry, 2008, Vol. 421, Part 2, pp. 171–174. © Pleiades Publishing, Ltd., 2008. Original Russian Text © E.N. Golubeva, A.V. Lobanov, V.I. Pergushov, N.A. Chumakova, A.I. Kokorin, 2008, published in Doklady Akademii Nauk, 2008, Vol. 421, No. 5, pp. 630–633. CHEMISTRY Copper(II) Organic Compounds as Intermediates of Photochemical Transformations of Quaternary Ammonium Tetrachlorocuprates a a a a b E. N. Golubeva , A. V. Lobanov , V. I. Pergushov , N. A. Chumakova , and A. I. Kokorin Presented by Academician A.L. Buchachenko February 5, 2008 Received February 11, 2008 DOI: 10.1134/S0012500808080016 Stable organometallic compounds with a Cu(II)–C σ and bimolecular processes [3] bond have not been described [1]. Pulse radiolysis and + + 2CuR 2Cu + R , photolysis of divalent copper salts in aqueous solutions [2, 3] and in n-donor solvents [4] gave short-lived copper + + 2+ complexes with organic radicals in which the copper oxi- CuR + H O Cu + RH + H O, 3 2 dation state was presumably two. Dissociation [2] were considered as the key routes for the destruction of + + • CuR Cu + R these complexes. 3.0 405 nm 1.2 1.0 2.5 0.8 0.6 2.0

Journal

Doklady ChemistrySpringer Journals

Published: Aug 21, 2008

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