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Composition of Outer-Sphere Cations as a Tool for Control over the Chemical and Phase Composition of the Products of Electrochemical Synthesis in Niobium-Containing Melts

Composition of Outer-Sphere Cations as a Tool for Control over the Chemical and Phase Composition... Doklady Chemistry, Vol. 382, Nos. 1–3, 2002, pp. 5–8. Translated from Doklady Akademii Nauk, Vol. 382, No. 1, 2002, pp. 66–70. Original Russian Text Copyright © 2002 by Grinevich, Arakcheeva, Kuznetsov, Kalinnikov. CHEMISTRY Composition of Outer-Sphere Cations as a Tool for Control over the Chemical and Phase Composition of the Products of Electrochemical Synthesis in Niobium-Containing Melts V. V. Grinevich*, A. V. Arakcheeva*, S. A. Kuznetsov**, and Academician V. T. Kalinnikov** Received September 10, 2001 The electrochemical behavior of niobium and the responding cathodic products differ in chemical and state of its ions in molten salts has been rather well doc- phase composition [3]. umented (see review [1] and original works [2–9]). At the same time, the role of the cationic composi- tion of a solvent in the electrochemical process has Nearly all of these works refer to chemical and elec- remained out of focus. This is reflected in a limited and trochemical processes in salt systems containing both nonfunctional choice of solvents employed in practice. the oxygen-free niobium halide complexes and its oxo- These are, as a rule, an equimolar NaCl–KCl mixture halide complexes. The latter can form in the melts of (occasionally with CsCl additions) among chloride http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Doklady Chemistry Springer Journals

Composition of Outer-Sphere Cations as a Tool for Control over the Chemical and Phase Composition of the Products of Electrochemical Synthesis in Niobium-Containing Melts

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References (4)

Publisher
Springer Journals
Copyright
Copyright © 2002 by MAIK “Nauka/Interperiodica”
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
0012-5008
eISSN
1608-3113
DOI
10.1023/A:1013828119202
Publisher site
See Article on Publisher Site

Abstract

Doklady Chemistry, Vol. 382, Nos. 1–3, 2002, pp. 5–8. Translated from Doklady Akademii Nauk, Vol. 382, No. 1, 2002, pp. 66–70. Original Russian Text Copyright © 2002 by Grinevich, Arakcheeva, Kuznetsov, Kalinnikov. CHEMISTRY Composition of Outer-Sphere Cations as a Tool for Control over the Chemical and Phase Composition of the Products of Electrochemical Synthesis in Niobium-Containing Melts V. V. Grinevich*, A. V. Arakcheeva*, S. A. Kuznetsov**, and Academician V. T. Kalinnikov** Received September 10, 2001 The electrochemical behavior of niobium and the responding cathodic products differ in chemical and state of its ions in molten salts has been rather well doc- phase composition [3]. umented (see review [1] and original works [2–9]). At the same time, the role of the cationic composi- tion of a solvent in the electrochemical process has Nearly all of these works refer to chemical and elec- remained out of focus. This is reflected in a limited and trochemical processes in salt systems containing both nonfunctional choice of solvents employed in practice. the oxygen-free niobium halide complexes and its oxo- These are, as a rule, an equimolar NaCl–KCl mixture halide complexes. The latter can form in the melts of (occasionally with CsCl additions) among chloride

Journal

Doklady Chemistry – Springer Journals

Published: Oct 10, 2004

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