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ISSN 00125008, Doklady Chemistry, 2010, Vol. 431, Part 1, pp. 89–93. © Pleiades Publishing, Ltd., 2010. Original Russian Text © Yu.B. Monakov, R.M. Islamova, G.R. Sadykova, Ya.Z. Voloshinb, I.G. Makarenko, A.Yu. Lebedev, Yu.N. Bubnov, 2010, published in Doklady Akademii Nauk, 2010, Vol. 431, No. 3, pp. 351–355. CHEMISTRY Clathrochelates as Components of New Initiating Systems for Complex–Radical Polymerization of Methyl Methacrylate a a a b Academician Yu. B. Monakov , R. M. Islamova , G. R. Sadykova , Ya. Z. Voloshin , b b I. G. Makarenko , A. Yu. Lebedev , and Academician Yu. N. Bubnov Received September 30, 2009 DOI: 10.1134/S0012500810030079 The development of macromolecular chemistry is polymerization initiation, as well as with vinyl mono inseparably linked with the search for the possibility to mers and/or macroradicals at the stage of chain prop enhance the selectivity of polymerization reactions agation. The use of alkyl and olefin apical substituents and to control the formation of the molecular and makes it possible to considerably enhance the solubil supramolecular structure of monomers. For radical ity of metal complexes in organic media (mainly, in polymerization, of crucial importance in the tailor monomers) and carry out bulk polymerization. made synthesis of regular
Doklady Chemistry – Springer Journals
Published: Mar 23, 2010
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