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- Publisher
- Springer Journals
- Copyright
- Copyright © Pleiades Publishing, Ltd. 2021. ISSN 0012-5008, Doklady Chemistry, 2021, Vol. 500, Part 2, pp. 205–208. © Pleiades Publishing, Ltd., 2021. Russian Text © The Author(s), 2021, published in Doklady Rossiiskoi Akademii Nauk. Khimiya, Nauki o Materialakh, 2021, Vol. 500, pp. 35–39.
- ISSN
- 0012-5008
- eISSN
- 1608-3113
- DOI
- 10.1134/s0012500821100025
- Publisher site
- See Article on Publisher Site
Abstract
The reaction of sulfonium closo-decaborate derivatives containing carboxyl groups with sulfuryl chloride SO2Cl2 as a halogenating agent was studied. The reaction gave fully halogenated derivatives of the closo-decaborate anion, (n-Bu4N)[2-B10Cl9SR2] (R = –CH2COOEt, –CH2COOH), which was confirmed by 11B, 1H, and 13C NMR and IR spectral data. The structure of the [2-B10Cl9S(CH2COOEt)2]– anion was established using single crystal X-ray diffraction.
Journal
Doklady Chemistry – Springer Journals
Published: Oct 1, 2021
Keywords: closo-decaborate anion; boron clusters; sulfonium derivatives; halogenation