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Catalytic Action of Ammonia on the Mechanochemical Synthesis of Intermetallic Hydrides at High Gas Pressure

Catalytic Action of Ammonia on the Mechanochemical Synthesis of Intermetallic Hydrides at High... Doklady Chemistry, Vol. 402, Part 2, 2005, pp. 101–104. Translated from Doklady Akademii Nauk, Vol. 402, No. 6, 2005, pp. 771–774. Original Russian Text Copyright © 2005 by Goidin, Molchanov, Buyanov. CHEMISTRY Catalytic Action of Ammonia on the Mechanochemical Synthesis of Intermetallic Hydrides at High Gas Pressure V. V. Goidin, V. V. Molchanov, and Corresponding Member of the RAS R. A. Buyanov Received March 1, 2005 Hydrides of intermetallic compounds are used as mechanochemical synthesis of intermetallic hydrides at hydrogen accumulating systems. They also exhibit cat- high gas pressure. alytic activities in reactions involving hydrogen, as has The mechanical activation was carried out in an been reported in numerous publications [1–6]. Until the AGO-2 planetary mill (developed at the Institute of mid-1980s, two methods for the preparation of interme- Solid-State Chemistry and Mechanochemistry, Sibe- tallic hydrides were known, namely, by hydrogenation rian Division of the RAS) with steel balls 5–10 mm in of alloys obtained by the pyrometallurgical process [1–3] diameter at a drum rotation frequency of 10–17 rps and and via organomagnesium compounds [4]. The draw- a drum volume of 150 cm . The atmosphere in the backs of the former method are the high energy con- drums http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Doklady Chemistry Springer Journals

Catalytic Action of Ammonia on the Mechanochemical Synthesis of Intermetallic Hydrides at High Gas Pressure

Doklady Chemistry , Volume 402 (6) – Jul 26, 2005

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References (4)

Publisher
Springer Journals
Copyright
Copyright © 2005 by MAIK “Nauka/Interperiodica”
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
0012-5008
eISSN
1608-3113
DOI
10.1007/s10631-005-0045-y
Publisher site
See Article on Publisher Site

Abstract

Doklady Chemistry, Vol. 402, Part 2, 2005, pp. 101–104. Translated from Doklady Akademii Nauk, Vol. 402, No. 6, 2005, pp. 771–774. Original Russian Text Copyright © 2005 by Goidin, Molchanov, Buyanov. CHEMISTRY Catalytic Action of Ammonia on the Mechanochemical Synthesis of Intermetallic Hydrides at High Gas Pressure V. V. Goidin, V. V. Molchanov, and Corresponding Member of the RAS R. A. Buyanov Received March 1, 2005 Hydrides of intermetallic compounds are used as mechanochemical synthesis of intermetallic hydrides at hydrogen accumulating systems. They also exhibit cat- high gas pressure. alytic activities in reactions involving hydrogen, as has The mechanical activation was carried out in an been reported in numerous publications [1–6]. Until the AGO-2 planetary mill (developed at the Institute of mid-1980s, two methods for the preparation of interme- Solid-State Chemistry and Mechanochemistry, Sibe- tallic hydrides were known, namely, by hydrogenation rian Division of the RAS) with steel balls 5–10 mm in of alloys obtained by the pyrometallurgical process [1–3] diameter at a drum rotation frequency of 10–17 rps and and via organomagnesium compounds [4]. The draw- a drum volume of 150 cm . The atmosphere in the backs of the former method are the high energy con- drums

Journal

Doklady ChemistrySpringer Journals

Published: Jul 26, 2005

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