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Experimental evidence is presented that semiconductor–metal eutectics with a low content of the metallic phase (4 vol %) are similar in electronic structure to inhomogeneous semiconductors. The microstructure of undoped and Te-doped GaSb–V2Ga5 and GaSb–GaV3Sb5 eutectic alloys is examined, and the Hall mobility of carriers in these alloys is determined. The anomalous temperature variation of Hall mobility in GaSb–V2Ga5 (μ ∼ T 2) and GaSb–GaV3Sb5 (μ ∼ T 5) is interpreted in terms of infinite clusters ofn-type metallic inclusions embedded in a p-type semiconductor matrix and interconnected through overlapping inhomogeneous interfaces. It seems likely that the difference in conductivity type between the semiconductor matrix and the infinite clusters gives rise to a random large-scale potential relief. Te compensation of GaSb in the eutectic alloys causes the Hall mobility to vary more rapidly with temperature, μ ∼T 3 to T 10 , which is interpreted as due to an increase in the amplitude of the random large-scale potential relief, the formation of infinite clusters, and partial compensation of unintentional acceptor doping in the semiconductor matrix.
Inorganic Materials – Springer Journals
Published: Oct 6, 2004
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